Compositional analysis and depth profiling of thin film CrO2 by heavy ion ERDA and standard RBS: a comparison

• Published in: Materials characterization 2012-08, Vol.70, p.42-47
• Main Authors: Khamlich, S., Msimanga, M., Pineda-Vargas, C.A., Nuru, Z.Y., McCrindle, R., Maaza, M.
• Format: Article
• Language: English
• Subjects: Chromium; Chromium dioxide; Cross-disciplinary physics: materials science; rheology; Dioxides; Exact sciences and technology; HI-ERDA; Materials science; Methods of deposition of films and coatings; film growth and epitaxy; Nuclei; Phase diagrams and microstructures developed by solidification and solid-solid phase transformations; Physics; RBS; Solidification; Spectrometry; Spectroscopy; Synthesis; Thin films; Vaporization
• ISSN: 1044-5803; 1873-4189
• DOI: 10.1016/j.matchar.2012.05.003

Chromium dioxide (CrO2) thin film has generated considerable interest in applied research due to the wide variety of its technological applications. It has been extensively investigated in recent years, attracting the attention of researchers working on spintronic heterostructures and in the magnetic recording industry. However, its synthesis is usually a difficult task due to its metastable nature and various synthesis techniques are being investigated. In this work a polycrystalline thin film of CrO2 was prepared by electron beam vaporization of Cr2O3 onto a Si substrate. The polycrystalline structure was confirmed through XRD analysis. The stoichiometry and elemental depth distribution of the deposited film were measured by ion beam nuclear analytical techniques heavy ion elastic recoil detection analysis (ERDA) and Rutherford backscattering spectrometry (RBS), which both have relative advantage over non-nuclear spectrometries in that they can readily provide quantitative information about the concentration and distribution of different atomic species in a layer. Moreover, the analysis carried out highlights the importance of complementary usage of the two techniques to obtain a more complete description of elemental content and depth distribution in thin films. Heavy ion elastic recoil detection analysis (ERDA) and Rutherford backscattering spectrometry (RBS) both have relative advantage over non-nuclear spectrometries in that they can readily provide quantitative information about the concentration and distribution of different atomic species in a layer. [Display omitted] ► Thin films of CrO2 have been grown by e-beam evaporation of Cr2O3 target in vacuum. ► The composition was determined by heavy ion—ERDA and RBS. ► HI-ERDA and RBS provided information on the light and heavy elements, respectively.