Click chemistry and electro-grafting onto colloidally templated conducting polymer arrays

Herein we developed a new approach of creating topologically and well-defined patterned polymeric surfaces via the “grafting to” approach. This was accomplished by either using colloidally templated “clickable” arrays, whereby the chemistry was performed directly onto the pattern or by subsequent ba...

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Bibliographic Details
Published in:Polymer (Guilford) 2012-07, Vol.53 (15), p.3124-3134
Main Authors: Foster, Edward L., Bunha, Ajaykumar, Advincula, Rigoberto
Format: Article
Language:English
Subjects:
Applied sciences
Arrays
Backfilling
Colloid chemistry
Colloidal templating
Colloids
Conducting polymers
Electrodeposition
Exact sciences and technology
Gates
Glycols
Grafting
Ion gate
Physicochemistry of polymers
Polymerization
Polymers and radiations
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Summary:Herein we developed a new approach of creating topologically and well-defined patterned polymeric surfaces via the “grafting to” approach. This was accomplished by either using colloidally templated “clickable” arrays, whereby the chemistry was performed directly onto the pattern or by subsequent backfilling with azido terminated SAM's. Similarly, direct grafting of electroactive temperature responsive oligo(ethylene glycol) methacrylic polymers to colloidally templated surfaces allowed for tunable ion gate formation. [Display omitted]
ISSN:0032-3861
1873-2291
DOI:10.1016/j.polymer.2012.05.040