New Method To Access Hyperbranched Polymers with Uniform Structure via One-Pot Polymerization of Inimer in Microemulsion

A facile approach is presented for successful synthesis of hyperbranched polymers with high molecular weight and uniform structure by a one-pot polymerization of an inimer in a microemulsion. The segregated space in the microemulsion confined the inimer polymerization and particularly the polymer–po...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the American Chemical Society 2012-09, Vol.134 (38), p.15680-15683
Main Authors: Min, Ke, Gao, Haifeng
Format: Article
Language:English
Subjects:
Emulsions
Magnetic Resonance Spectroscopy
Molecular Structure
Polymers - chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a315t-a520f47cc4d1b0f3dfce61794971f503d2a149ab3f4a5d1c645f7a6dcfcec37f3
cites cdi_FETCH-LOGICAL-a315t-a520f47cc4d1b0f3dfce61794971f503d2a149ab3f4a5d1c645f7a6dcfcec37f3
container_end_page 15683
container_issue 38
container_start_page 15680
container_title Journal of the American Chemical Society
container_volume 134
creator Min, Ke
Gao, Haifeng
description A facile approach is presented for successful synthesis of hyperbranched polymers with high molecular weight and uniform structure by a one-pot polymerization of an inimer in a microemulsion. The segregated space in the microemulsion confined the inimer polymerization and particularly the polymer–polymer reaction within discrete nanoparticles. At the end of polymerization, each nanoparticle contained one hyperbranched polymer that had thousands of inimer units and low polydispersity. The hyperbranched polymers were used as multifunctional macroinitiators for synthesis of “hyper-star” polymers. When a degradable inimer was applied, the hyper-stars showed fast degradation into linear polymer chains with low molecular weight.
doi_str_mv 10.1021/ja307174h
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1080882225</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1080882225</sourcerecordid><originalsourceid>FETCH-LOGICAL-a315t-a520f47cc4d1b0f3dfce61794971f503d2a149ab3f4a5d1c645f7a6dcfcec37f3</originalsourceid><addsrcrecordid>eNpt0MtKAzEUBuAgiq3VhS8g2Qi6GE0y92UpagutLdiuh0wuTMpMUpMZa316I72sXIXkfPzk_ADcYvSEEcHPaxqiFKdRdQb6OCYoiDFJzkEfIUSCNEvCHrhybu2vEcnwJegRkicki3EffL-LLZyJtjIcLg0cMiacg-PdRtjSUs0qweHC1LtGWAe3qq3gSitpbAM_WtuxtrMCfikK51oEC9MerfqhrTIaGgknWvkHqDScKWaNaLra-dE1uJC0duLmcA7A6vVlORoH0_nbZDScBjTEcRtQv46MUsYijkskQy6ZSHCaR3mKZYxCTiiOclqGMqIxxyyJYpnShDPvWJjKcAAe9rkbaz474dqiUY6JuqZamM4VGGUoywghsaePe-q_6ZwVsthY1VC786j4K7o4Fe3t3SG2KxvBT_LYrAf3e0CZK9ams9pv-U_QLyqBhnI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1080882225</pqid></control><display><type>article</type><title>New Method To Access Hyperbranched Polymers with Uniform Structure via One-Pot Polymerization of Inimer in Microemulsion</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Min, Ke ; Gao, Haifeng</creator><creatorcontrib>Min, Ke ; Gao, Haifeng</creatorcontrib><description>A facile approach is presented for successful synthesis of hyperbranched polymers with high molecular weight and uniform structure by a one-pot polymerization of an inimer in a microemulsion. The segregated space in the microemulsion confined the inimer polymerization and particularly the polymer–polymer reaction within discrete nanoparticles. At the end of polymerization, each nanoparticle contained one hyperbranched polymer that had thousands of inimer units and low polydispersity. The hyperbranched polymers were used as multifunctional macroinitiators for synthesis of “hyper-star” polymers. When a degradable inimer was applied, the hyper-stars showed fast degradation into linear polymer chains with low molecular weight.</description><identifier>ISSN: 0002-7863</identifier><identifier>EISSN: 1520-5126</identifier><identifier>DOI: 10.1021/ja307174h</identifier><identifier>PMID: 22962851</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Emulsions ; Magnetic Resonance Spectroscopy ; Molecular Structure ; Polymers - chemistry</subject><ispartof>Journal of the American Chemical Society, 2012-09, Vol.134 (38), p.15680-15683</ispartof><rights>Copyright © 2012 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a315t-a520f47cc4d1b0f3dfce61794971f503d2a149ab3f4a5d1c645f7a6dcfcec37f3</citedby><cites>FETCH-LOGICAL-a315t-a520f47cc4d1b0f3dfce61794971f503d2a149ab3f4a5d1c645f7a6dcfcec37f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22962851$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Min, Ke</creatorcontrib><creatorcontrib>Gao, Haifeng</creatorcontrib><title>New Method To Access Hyperbranched Polymers with Uniform Structure via One-Pot Polymerization of Inimer in Microemulsion</title><title>Journal of the American Chemical Society</title><addtitle>J. Am. Chem. Soc</addtitle><description>A facile approach is presented for successful synthesis of hyperbranched polymers with high molecular weight and uniform structure by a one-pot polymerization of an inimer in a microemulsion. The segregated space in the microemulsion confined the inimer polymerization and particularly the polymer–polymer reaction within discrete nanoparticles. At the end of polymerization, each nanoparticle contained one hyperbranched polymer that had thousands of inimer units and low polydispersity. The hyperbranched polymers were used as multifunctional macroinitiators for synthesis of “hyper-star” polymers. When a degradable inimer was applied, the hyper-stars showed fast degradation into linear polymer chains with low molecular weight.</description><subject>Emulsions</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Molecular Structure</subject><subject>Polymers - chemistry</subject><issn>0002-7863</issn><issn>1520-5126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNpt0MtKAzEUBuAgiq3VhS8g2Qi6GE0y92UpagutLdiuh0wuTMpMUpMZa316I72sXIXkfPzk_ADcYvSEEcHPaxqiFKdRdQb6OCYoiDFJzkEfIUSCNEvCHrhybu2vEcnwJegRkicki3EffL-LLZyJtjIcLg0cMiacg-PdRtjSUs0qweHC1LtGWAe3qq3gSitpbAM_WtuxtrMCfikK51oEC9MerfqhrTIaGgknWvkHqDScKWaNaLra-dE1uJC0duLmcA7A6vVlORoH0_nbZDScBjTEcRtQv46MUsYijkskQy6ZSHCaR3mKZYxCTiiOclqGMqIxxyyJYpnShDPvWJjKcAAe9rkbaz474dqiUY6JuqZamM4VGGUoywghsaePe-q_6ZwVsthY1VC786j4K7o4Fe3t3SG2KxvBT_LYrAf3e0CZK9ams9pv-U_QLyqBhnI</recordid><startdate>20120926</startdate><enddate>20120926</enddate><creator>Min, Ke</creator><creator>Gao, Haifeng</creator><general>American Chemical Society</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20120926</creationdate><title>New Method To Access Hyperbranched Polymers with Uniform Structure via One-Pot Polymerization of Inimer in Microemulsion</title><author>Min, Ke ; Gao, Haifeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a315t-a520f47cc4d1b0f3dfce61794971f503d2a149ab3f4a5d1c645f7a6dcfcec37f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Emulsions</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Molecular Structure</topic><topic>Polymers - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Min, Ke</creatorcontrib><creatorcontrib>Gao, Haifeng</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of the American Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Min, Ke</au><au>Gao, Haifeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New Method To Access Hyperbranched Polymers with Uniform Structure via One-Pot Polymerization of Inimer in Microemulsion</atitle><jtitle>Journal of the American Chemical Society</jtitle><addtitle>J. Am. Chem. Soc</addtitle><date>2012-09-26</date><risdate>2012</risdate><volume>134</volume><issue>38</issue><spage>15680</spage><epage>15683</epage><pages>15680-15683</pages><issn>0002-7863</issn><eissn>1520-5126</eissn><abstract>A facile approach is presented for successful synthesis of hyperbranched polymers with high molecular weight and uniform structure by a one-pot polymerization of an inimer in a microemulsion. The segregated space in the microemulsion confined the inimer polymerization and particularly the polymer–polymer reaction within discrete nanoparticles. At the end of polymerization, each nanoparticle contained one hyperbranched polymer that had thousands of inimer units and low polydispersity. The hyperbranched polymers were used as multifunctional macroinitiators for synthesis of “hyper-star” polymers. When a degradable inimer was applied, the hyper-stars showed fast degradation into linear polymer chains with low molecular weight.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>22962851</pmid><doi>10.1021/ja307174h</doi><tpages>4</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0002-7863
ispartof Journal of the American Chemical Society, 2012-09, Vol.134 (38), p.15680-15683
issn 0002-7863
1520-5126
language eng
recordid cdi_proquest_miscellaneous_1080882225
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Emulsions
Magnetic Resonance Spectroscopy
Molecular Structure
Polymers - chemistry
title New Method To Access Hyperbranched Polymers with Uniform Structure via One-Pot Polymerization of Inimer in Microemulsion
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T14%3A29%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=New%20Method%20To%20Access%20Hyperbranched%20Polymers%20with%20Uniform%20Structure%20via%20One-Pot%20Polymerization%20of%20Inimer%20in%20Microemulsion&rft.jtitle=Journal%20of%20the%20American%20Chemical%20Society&rft.au=Min,%20Ke&rft.date=2012-09-26&rft.volume=134&rft.issue=38&rft.spage=15680&rft.epage=15683&rft.pages=15680-15683&rft.issn=0002-7863&rft.eissn=1520-5126&rft_id=info:doi/10.1021/ja307174h&rft_dat=%3Cproquest_cross%3E1080882225%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a315t-a520f47cc4d1b0f3dfce61794971f503d2a149ab3f4a5d1c645f7a6dcfcec37f3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1080882225&rft_id=info:pmid/22962851&rfr_iscdi=true