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Effect of Ho Content on Microstructure and Ferroelectric Properties of Bi sub(4-x)Ho sub(x)Ti sub(3)O sub(12) Thin Films Prepared by Sol-Gel Method
Bi sub(4-x)Ho sub(x)Ti sub(3)O sub(12) (BHT-x) thin films with Ho content x=0.2, 0.4, 0.6, 0.8, and 1.0 were prepared on Pt-Ti-SiO sub(2)-Si substrates by a sol-gel method. Effects of Ho contents on the microstructure and ferroelectric properties of BHT-x thin films were investigated. All the BHT-x...
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Published in: | Journal of the American Ceramic Society 2008-10, Vol.91 (10), p.3280-3284 |
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creator | Guo, Dongyun Zhang, Lianmeng Li, Meiya Liu, Jun Yu, Benfang |
description | Bi sub(4-x)Ho sub(x)Ti sub(3)O sub(12) (BHT-x) thin films with Ho content x=0.2, 0.4, 0.6, 0.8, and 1.0 were prepared on Pt-Ti-SiO sub(2)-Si substrates by a sol-gel method. Effects of Ho contents on the microstructure and ferroelectric properties of BHT-x thin films were investigated. All the BHT-x samples consist of the Bi-layered Aurivillius phase. The lattice constants along the a, b, and c axes decrease with the increase of x. The remanent polarization (2P sub(r)) and dielectric constant (e sub(r)) increase firstly and then decreases with the increase of the Ho content, while the leakage current density shows opposite trend. BHT-0.4 film exhibits the best electrical properties with 2P sub(r) 44.2 kC-cm super(2), 2E sub(c) 323.7 kV-cm, e sub(r) 489 (at 1 MHz), dielectric loss 0.018 (at 1 MHz), leakage current density 8.0 10 super(-8) A-cm super(2) (under 200 kV-cm), as well as the strongest fatigue resistance (the polarization loss is only 3% after 4.46 10 super(9) switching cycles). |
doi_str_mv | 10.1111/j.1551-2916.2008.02664.x |
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Effects of Ho contents on the microstructure and ferroelectric properties of BHT-x thin films were investigated. All the BHT-x samples consist of the Bi-layered Aurivillius phase. The lattice constants along the a, b, and c axes decrease with the increase of x. The remanent polarization (2P sub(r)) and dielectric constant (e sub(r)) increase firstly and then decreases with the increase of the Ho content, while the leakage current density shows opposite trend. BHT-0.4 film exhibits the best electrical properties with 2P sub(r) 44.2 kC-cm super(2), 2E sub(c) 323.7 kV-cm, e sub(r) 489 (at 1 MHz), dielectric loss 0.018 (at 1 MHz), leakage current density 8.0 10 super(-8) A-cm super(2) (under 200 kV-cm), as well as the strongest fatigue resistance (the polarization loss is only 3% after 4.46 10 super(9) switching cycles).</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/j.1551-2916.2008.02664.x</identifier><language>eng</language><subject>Density ; Ferroelectric materials ; Ferroelectricity ; Leakage current ; Microstructure ; Polarization ; Sol gel process ; Thin films</subject><ispartof>Journal of the American Ceramic Society, 2008-10, Vol.91 (10), p.3280-3284</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Guo, Dongyun</creatorcontrib><creatorcontrib>Zhang, Lianmeng</creatorcontrib><creatorcontrib>Li, Meiya</creatorcontrib><creatorcontrib>Liu, Jun</creatorcontrib><creatorcontrib>Yu, Benfang</creatorcontrib><title>Effect of Ho Content on Microstructure and Ferroelectric Properties of Bi sub(4-x)Ho sub(x)Ti sub(3)O sub(12) Thin Films Prepared by Sol-Gel Method</title><title>Journal of the American Ceramic Society</title><description>Bi sub(4-x)Ho sub(x)Ti sub(3)O sub(12) (BHT-x) thin films with Ho content x=0.2, 0.4, 0.6, 0.8, and 1.0 were prepared on Pt-Ti-SiO sub(2)-Si substrates by a sol-gel method. Effects of Ho contents on the microstructure and ferroelectric properties of BHT-x thin films were investigated. All the BHT-x samples consist of the Bi-layered Aurivillius phase. The lattice constants along the a, b, and c axes decrease with the increase of x. The remanent polarization (2P sub(r)) and dielectric constant (e sub(r)) increase firstly and then decreases with the increase of the Ho content, while the leakage current density shows opposite trend. BHT-0.4 film exhibits the best electrical properties with 2P sub(r) 44.2 kC-cm super(2), 2E sub(c) 323.7 kV-cm, e sub(r) 489 (at 1 MHz), dielectric loss 0.018 (at 1 MHz), leakage current density 8.0 10 super(-8) A-cm super(2) (under 200 kV-cm), as well as the strongest fatigue resistance (the polarization loss is only 3% after 4.46 10 super(9) switching cycles).</description><subject>Density</subject><subject>Ferroelectric materials</subject><subject>Ferroelectricity</subject><subject>Leakage current</subject><subject>Microstructure</subject><subject>Polarization</subject><subject>Sol gel process</subject><subject>Thin films</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqVTL1OwzAQthBIhMI73NgMDrabpMlK1dClAqnZqzS5qK5cO9iOFJ6DF8aliJ1bvvt-CQHOEh7u-ZTwLONUlDxPBGNFwkSep8l0Q6I_45ZEjDFBl4Vg9-TBuVOgvCzSiHyt-x5bD6aHjYGV0R51YBq2srXGeTu2frQIje6gQmsNqhC3soV3awa0XqK7lF8kuPEwT-kUh53LO8X1VVvEbz_IRQz1UWqopDq70MehsdjB4RN2RtFXVLBFfzTdI7nrG-Xw6RdnZF6t69WGDtZ8jOj8_ixdi0o1Gs3o9pwVQjCxzMrFP6Lf3g9gKw</recordid><startdate>20081001</startdate><enddate>20081001</enddate><creator>Guo, Dongyun</creator><creator>Zhang, Lianmeng</creator><creator>Li, Meiya</creator><creator>Liu, Jun</creator><creator>Yu, Benfang</creator><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20081001</creationdate><title>Effect of Ho Content on Microstructure and Ferroelectric Properties of Bi sub(4-x)Ho sub(x)Ti sub(3)O sub(12) Thin Films Prepared by Sol-Gel Method</title><author>Guo, Dongyun ; Zhang, Lianmeng ; Li, Meiya ; Liu, Jun ; Yu, Benfang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_10822027593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>Density</topic><topic>Ferroelectric materials</topic><topic>Ferroelectricity</topic><topic>Leakage current</topic><topic>Microstructure</topic><topic>Polarization</topic><topic>Sol gel process</topic><topic>Thin films</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo, Dongyun</creatorcontrib><creatorcontrib>Zhang, Lianmeng</creatorcontrib><creatorcontrib>Li, Meiya</creatorcontrib><creatorcontrib>Liu, Jun</creatorcontrib><creatorcontrib>Yu, Benfang</creatorcontrib><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Dongyun</au><au>Zhang, Lianmeng</au><au>Li, Meiya</au><au>Liu, Jun</au><au>Yu, Benfang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of Ho Content on Microstructure and Ferroelectric Properties of Bi sub(4-x)Ho sub(x)Ti sub(3)O sub(12) Thin Films Prepared by Sol-Gel Method</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>2008-10-01</date><risdate>2008</risdate><volume>91</volume><issue>10</issue><spage>3280</spage><epage>3284</epage><pages>3280-3284</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>Bi sub(4-x)Ho sub(x)Ti sub(3)O sub(12) (BHT-x) thin films with Ho content x=0.2, 0.4, 0.6, 0.8, and 1.0 were prepared on Pt-Ti-SiO sub(2)-Si substrates by a sol-gel method. Effects of Ho contents on the microstructure and ferroelectric properties of BHT-x thin films were investigated. All the BHT-x samples consist of the Bi-layered Aurivillius phase. The lattice constants along the a, b, and c axes decrease with the increase of x. The remanent polarization (2P sub(r)) and dielectric constant (e sub(r)) increase firstly and then decreases with the increase of the Ho content, while the leakage current density shows opposite trend. BHT-0.4 film exhibits the best electrical properties with 2P sub(r) 44.2 kC-cm super(2), 2E sub(c) 323.7 kV-cm, e sub(r) 489 (at 1 MHz), dielectric loss 0.018 (at 1 MHz), leakage current density 8.0 10 super(-8) A-cm super(2) (under 200 kV-cm), as well as the strongest fatigue resistance (the polarization loss is only 3% after 4.46 10 super(9) switching cycles).</abstract><doi>10.1111/j.1551-2916.2008.02664.x</doi></addata></record> |
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subjects | Density Ferroelectric materials Ferroelectricity Leakage current Microstructure Polarization Sol gel process Thin films |
title | Effect of Ho Content on Microstructure and Ferroelectric Properties of Bi sub(4-x)Ho sub(x)Ti sub(3)O sub(12) Thin Films Prepared by Sol-Gel Method |
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