Loading…
Structure, infrared and Raman spectroscopic studies of new Sr0.50SbFe(PO4)3 and SrSb0.50Fe1.50(PO4)3 Nasicon phases
Two newly synthesised Sr 0.50 SbFe(PO 4 ) 3 [Sr 0.5 .] and SrSb 0.50 Fe 1.50 (PO 4 ) 3 [Sr.] phases were obtained by conventional solid-state reaction techniques at 1000 °C in air atmosphere. Their crystallographic structures were determined at room temperature from X-ray powder diffraction (XRPD) d...
Saved in:
| Published in: | Journal of materials science 2012-02, Vol.47 (3), p.1354-1364 |
|---|---|
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c1940-7f8807fa1981022ea262274e6e10a2238434c3c59d745d4cfafc92ebbc23dd733 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c1940-7f8807fa1981022ea262274e6e10a2238434c3c59d745d4cfafc92ebbc23dd733 |
| container_end_page | 1364 |
| container_issue | 3 |
| container_start_page | 1354 |
| container_title | Journal of materials science |
| container_volume | 47 |
| creator | Aatiq, Abderrahim Tigha, My Rachid Benmokhtar, Said |
| description | Two newly synthesised Sr
0.50
SbFe(PO
4
)
3
[Sr
0.5
.] and SrSb
0.50
Fe
1.50
(PO
4
)
3
[Sr.] phases were obtained by conventional solid-state reaction techniques at 1000 °C in air atmosphere. Their crystallographic structures were determined at room temperature from X-ray powder diffraction (XRPD) data using the Rietveld analysis. Both compounds belong to the Nasicon structural family. [Sr
0.5
.] and [Sr.] crystallise in rhombohedral system with
and
space group, respectively. Hexagonal cell parameters for [Sr
0.5
.] and [Sr.] are:
a
= 8.227(1) Å,
c
= 22.767(2) Å and
a
= 8.339(1) Å,
c
= 22.704(2) Å, respectively. Sr
2+
and vacancies in {[Sr
0.50
]
3a
[□
0.50
]
3b
}
M1
SbFe(PO
4
)
3
are practically ordered within the two positions, 3a and 3b, of M1 sites. Structure refinements show also an ordered distribution of Sb
5+
and Fe
3+
ions within the Nasicon framework. Within the structure, each Sr
(3a)
O
6
octahedron shares two faces with two Fe
3+
O
6
octahedra and each vacancy (□
(3b)
O
6
) site is located between two Sb
5+
O
6
octahedra. In [Sr]
M1
Sb
0.50
Fe
1.50
(PO
4
)
3
compound, all M1 sites are occupied by Sr
2+
and the Sb
5+
and Fe
3+
ions are randomly distributed within the Nasicon framework. A Raman and infrared spectroscopic study was used to obtain further structural information about the nature of bonding in both selected compositions. |
| doi_str_mv | 10.1007/s10853-011-5910-0 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1082221623</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1082221623</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1940-7f8807fa1981022ea262274e6e10a2238434c3c59d745d4cfafc92ebbc23dd733</originalsourceid><addsrcrecordid>eNp1kUFr3DAQhUVpIds0PyA3QS8pxMloJK_sY1m6SWBpQpychVYetw67tquxCf33kbOBQKGXGZj53mOYJ8SpggsFYC9ZQZHrDJTK8lJBBh_EQuVWZ6YA_VEsABAzNEt1JD4zPwFAblEtBFdjnMI4RTqXbddEH6mWvqvlvd_7TvJAYYw9h35og-Rxqlti2Teyo2dZRbjIodqu6ezu1nzTr7oqVtt5vCaV6tvip-c29J0cfnsm_iI-NX7HdPLWj8Xj-sfD6jrb3F7drL5vsqBKA5ltigJs41VZqHQ9eVwiWkNLUuARdWG0CTrkZW1NXpvQ-CaUSNttQF3XVutjcXbwHWL_ZyIe3b7lQLud76if2KWXIaJa4ox-_Qd96qfYpescYl5aDSXMlDpQIb2EIzVuiO3ex7_Jys0xuEMMLsXg5hgcJA0eNJzY7hfFd-f_i14AZYCFzA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2259730903</pqid></control><display><type>article</type><title>Structure, infrared and Raman spectroscopic studies of new Sr0.50SbFe(PO4)3 and SrSb0.50Fe1.50(PO4)3 Nasicon phases</title><source>Springer Nature</source><creator>Aatiq, Abderrahim ; Tigha, My Rachid ; Benmokhtar, Said</creator><creatorcontrib>Aatiq, Abderrahim ; Tigha, My Rachid ; Benmokhtar, Said</creatorcontrib><description>Two newly synthesised Sr
0.50
SbFe(PO
4
)
3
[Sr
0.5
.] and SrSb
0.50
Fe
1.50
(PO
4
)
3
[Sr.] phases were obtained by conventional solid-state reaction techniques at 1000 °C in air atmosphere. Their crystallographic structures were determined at room temperature from X-ray powder diffraction (XRPD) data using the Rietveld analysis. Both compounds belong to the Nasicon structural family. [Sr
0.5
.] and [Sr.] crystallise in rhombohedral system with
and
space group, respectively. Hexagonal cell parameters for [Sr
0.5
.] and [Sr.] are:
a
= 8.227(1) Å,
c
= 22.767(2) Å and
a
= 8.339(1) Å,
c
= 22.704(2) Å, respectively. Sr
2+
and vacancies in {[Sr
0.50
]
3a
[□
0.50
]
3b
}
M1
SbFe(PO
4
)
3
are practically ordered within the two positions, 3a and 3b, of M1 sites. Structure refinements show also an ordered distribution of Sb
5+
and Fe
3+
ions within the Nasicon framework. Within the structure, each Sr
(3a)
O
6
octahedron shares two faces with two Fe
3+
O
6
octahedra and each vacancy (□
(3b)
O
6
) site is located between two Sb
5+
O
6
octahedra. In [Sr]
M1
Sb
0.50
Fe
1.50
(PO
4
)
3
compound, all M1 sites are occupied by Sr
2+
and the Sb
5+
and Fe
3+
ions are randomly distributed within the Nasicon framework. A Raman and infrared spectroscopic study was used to obtain further structural information about the nature of bonding in both selected compositions.</description><identifier>ISSN: 0022-2461</identifier><identifier>EISSN: 1573-4803</identifier><identifier>DOI: 10.1007/s10853-011-5910-0</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Bonding ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Classical Mechanics ; Crystal structure ; Crystallography ; Crystallography and Scattering Methods ; Diffraction ; Ferric ions ; Hexagonal cells ; Infrared ; Infrared spectroscopy ; Materials Science ; Phases ; Polymer Sciences ; Solid Mechanics ; Spectroscopic analysis ; Spectroscopy ; Vacancies ; X ray powder diffraction</subject><ispartof>Journal of materials science, 2012-02, Vol.47 (3), p.1354-1364</ispartof><rights>Springer Science+Business Media, LLC 2011</rights><rights>Journal of Materials Science is a copyright of Springer, (2011). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1940-7f8807fa1981022ea262274e6e10a2238434c3c59d745d4cfafc92ebbc23dd733</citedby><cites>FETCH-LOGICAL-c1940-7f8807fa1981022ea262274e6e10a2238434c3c59d745d4cfafc92ebbc23dd733</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Aatiq, Abderrahim</creatorcontrib><creatorcontrib>Tigha, My Rachid</creatorcontrib><creatorcontrib>Benmokhtar, Said</creatorcontrib><title>Structure, infrared and Raman spectroscopic studies of new Sr0.50SbFe(PO4)3 and SrSb0.50Fe1.50(PO4)3 Nasicon phases</title><title>Journal of materials science</title><addtitle>J Mater Sci</addtitle><description>Two newly synthesised Sr
0.50
SbFe(PO
4
)
3
[Sr
0.5
.] and SrSb
0.50
Fe
1.50
(PO
4
)
3
[Sr.] phases were obtained by conventional solid-state reaction techniques at 1000 °C in air atmosphere. Their crystallographic structures were determined at room temperature from X-ray powder diffraction (XRPD) data using the Rietveld analysis. Both compounds belong to the Nasicon structural family. [Sr
0.5
.] and [Sr.] crystallise in rhombohedral system with
and
space group, respectively. Hexagonal cell parameters for [Sr
0.5
.] and [Sr.] are:
a
= 8.227(1) Å,
c
= 22.767(2) Å and
a
= 8.339(1) Å,
c
= 22.704(2) Å, respectively. Sr
2+
and vacancies in {[Sr
0.50
]
3a
[□
0.50
]
3b
}
M1
SbFe(PO
4
)
3
are practically ordered within the two positions, 3a and 3b, of M1 sites. Structure refinements show also an ordered distribution of Sb
5+
and Fe
3+
ions within the Nasicon framework. Within the structure, each Sr
(3a)
O
6
octahedron shares two faces with two Fe
3+
O
6
octahedra and each vacancy (□
(3b)
O
6
) site is located between two Sb
5+
O
6
octahedra. In [Sr]
M1
Sb
0.50
Fe
1.50
(PO
4
)
3
compound, all M1 sites are occupied by Sr
2+
and the Sb
5+
and Fe
3+
ions are randomly distributed within the Nasicon framework. A Raman and infrared spectroscopic study was used to obtain further structural information about the nature of bonding in both selected compositions.</description><subject>Bonding</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Classical Mechanics</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Crystallography and Scattering Methods</subject><subject>Diffraction</subject><subject>Ferric ions</subject><subject>Hexagonal cells</subject><subject>Infrared</subject><subject>Infrared spectroscopy</subject><subject>Materials Science</subject><subject>Phases</subject><subject>Polymer Sciences</subject><subject>Solid Mechanics</subject><subject>Spectroscopic analysis</subject><subject>Spectroscopy</subject><subject>Vacancies</subject><subject>X ray powder diffraction</subject><issn>0022-2461</issn><issn>1573-4803</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNp1kUFr3DAQhUVpIds0PyA3QS8pxMloJK_sY1m6SWBpQpychVYetw67tquxCf33kbOBQKGXGZj53mOYJ8SpggsFYC9ZQZHrDJTK8lJBBh_EQuVWZ6YA_VEsABAzNEt1JD4zPwFAblEtBFdjnMI4RTqXbddEH6mWvqvlvd_7TvJAYYw9h35og-Rxqlti2Teyo2dZRbjIodqu6ezu1nzTr7oqVtt5vCaV6tvip-c29J0cfnsm_iI-NX7HdPLWj8Xj-sfD6jrb3F7drL5vsqBKA5ltigJs41VZqHQ9eVwiWkNLUuARdWG0CTrkZW1NXpvQ-CaUSNttQF3XVutjcXbwHWL_ZyIe3b7lQLud76if2KWXIaJa4ox-_Qd96qfYpescYl5aDSXMlDpQIb2EIzVuiO3ex7_Jys0xuEMMLsXg5hgcJA0eNJzY7hfFd-f_i14AZYCFzA</recordid><startdate>20120201</startdate><enddate>20120201</enddate><creator>Aatiq, Abderrahim</creator><creator>Tigha, My Rachid</creator><creator>Benmokhtar, Said</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20120201</creationdate><title>Structure, infrared and Raman spectroscopic studies of new Sr0.50SbFe(PO4)3 and SrSb0.50Fe1.50(PO4)3 Nasicon phases</title><author>Aatiq, Abderrahim ; Tigha, My Rachid ; Benmokhtar, Said</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1940-7f8807fa1981022ea262274e6e10a2238434c3c59d745d4cfafc92ebbc23dd733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Bonding</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Classical Mechanics</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Crystallography and Scattering Methods</topic><topic>Diffraction</topic><topic>Ferric ions</topic><topic>Hexagonal cells</topic><topic>Infrared</topic><topic>Infrared spectroscopy</topic><topic>Materials Science</topic><topic>Phases</topic><topic>Polymer Sciences</topic><topic>Solid Mechanics</topic><topic>Spectroscopic analysis</topic><topic>Spectroscopy</topic><topic>Vacancies</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Aatiq, Abderrahim</creatorcontrib><creatorcontrib>Tigha, My Rachid</creatorcontrib><creatorcontrib>Benmokhtar, Said</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>ProQuest Engineering Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering collection</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of materials science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Aatiq, Abderrahim</au><au>Tigha, My Rachid</au><au>Benmokhtar, Said</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure, infrared and Raman spectroscopic studies of new Sr0.50SbFe(PO4)3 and SrSb0.50Fe1.50(PO4)3 Nasicon phases</atitle><jtitle>Journal of materials science</jtitle><stitle>J Mater Sci</stitle><date>2012-02-01</date><risdate>2012</risdate><volume>47</volume><issue>3</issue><spage>1354</spage><epage>1364</epage><pages>1354-1364</pages><issn>0022-2461</issn><eissn>1573-4803</eissn><abstract>Two newly synthesised Sr
0.50
SbFe(PO
4
)
3
[Sr
0.5
.] and SrSb
0.50
Fe
1.50
(PO
4
)
3
[Sr.] phases were obtained by conventional solid-state reaction techniques at 1000 °C in air atmosphere. Their crystallographic structures were determined at room temperature from X-ray powder diffraction (XRPD) data using the Rietveld analysis. Both compounds belong to the Nasicon structural family. [Sr
0.5
.] and [Sr.] crystallise in rhombohedral system with
and
space group, respectively. Hexagonal cell parameters for [Sr
0.5
.] and [Sr.] are:
a
= 8.227(1) Å,
c
= 22.767(2) Å and
a
= 8.339(1) Å,
c
= 22.704(2) Å, respectively. Sr
2+
and vacancies in {[Sr
0.50
]
3a
[□
0.50
]
3b
}
M1
SbFe(PO
4
)
3
are practically ordered within the two positions, 3a and 3b, of M1 sites. Structure refinements show also an ordered distribution of Sb
5+
and Fe
3+
ions within the Nasicon framework. Within the structure, each Sr
(3a)
O
6
octahedron shares two faces with two Fe
3+
O
6
octahedra and each vacancy (□
(3b)
O
6
) site is located between two Sb
5+
O
6
octahedra. In [Sr]
M1
Sb
0.50
Fe
1.50
(PO
4
)
3
compound, all M1 sites are occupied by Sr
2+
and the Sb
5+
and Fe
3+
ions are randomly distributed within the Nasicon framework. A Raman and infrared spectroscopic study was used to obtain further structural information about the nature of bonding in both selected compositions.</abstract><cop>Boston</cop><pub>Springer US</pub><doi>10.1007/s10853-011-5910-0</doi><tpages>11</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-2461 |
| ispartof | Journal of materials science, 2012-02, Vol.47 (3), p.1354-1364 |
| issn | 0022-2461 1573-4803 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1082221623 |
| source | Springer Nature |
| subjects | Bonding Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Crystal structure Crystallography Crystallography and Scattering Methods Diffraction Ferric ions Hexagonal cells Infrared Infrared spectroscopy Materials Science Phases Polymer Sciences Solid Mechanics Spectroscopic analysis Spectroscopy Vacancies X ray powder diffraction |
| title | Structure, infrared and Raman spectroscopic studies of new Sr0.50SbFe(PO4)3 and SrSb0.50Fe1.50(PO4)3 Nasicon phases |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T02%3A40%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Structure,%20infrared%20and%20Raman%20spectroscopic%20studies%20of%20new%20Sr0.50SbFe(PO4)3%20and%20SrSb0.50Fe1.50(PO4)3%20Nasicon%20phases&rft.jtitle=Journal%20of%20materials%20science&rft.au=Aatiq,%20Abderrahim&rft.date=2012-02-01&rft.volume=47&rft.issue=3&rft.spage=1354&rft.epage=1364&rft.pages=1354-1364&rft.issn=0022-2461&rft.eissn=1573-4803&rft_id=info:doi/10.1007/s10853-011-5910-0&rft_dat=%3Cproquest_cross%3E1082221623%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c1940-7f8807fa1981022ea262274e6e10a2238434c3c59d745d4cfafc92ebbc23dd733%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2259730903&rft_id=info:pmid/&rfr_iscdi=true |