A General Synthetic Strategy for the Design of New BODIPY Fluorophores Based on Pyrroles with Polycondensed Aromatic and Metallocene Substituents

BODIPYrrole: A general strategy for the design of novel BODIPY fluorophores based on pyrroles with polycondensed aromatic and metallocene substituents has been developed. The strategy involves the acylation of the condensed substituent and treatment of the acylated derivative (as oxime) with acetyle...

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Bibliographic Details
Published in:Chemistry : a European journal 2011-03, Vol.17 (11), p.3069-3073
Main Authors: Yu. Schmidt, Elena, Zorina, Nadezhda V., Yu. Dvorko, Marina, Protsuk, Nadezhda I., Belyaeva, Kseniya V., Clavier, Gilles, Méallet-Renault, Rachel, Vu, Thanh T., Mikhaleva, Al'bina I., Trofimov, Boris A.
Format: Article
Language:English
Subjects:
BODIPY
Chemistry
condensed aromatics
fluorescence
pyrroles
synthetic methods
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Summary:BODIPYrrole: A general strategy for the design of novel BODIPY fluorophores based on pyrroles with polycondensed aromatic and metallocene substituents has been developed. The strategy involves the acylation of the condensed substituent and treatment of the acylated derivative (as oxime) with acetylene in MOH/DMSO (M=alkali metal) to give pyrroles that were then used for assembly of the BODIPY fluorophores (see scheme).
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201003242