Assembly of the First Fullerene-Type Metal-Organic Frameworks Using a Planar Five-Fold Coordination Node

Pump up the volume: Slow crystallization of Na[C5(CN)5], the unsolvated sodium salt of pentacyanocyclopentadienide, gives the first example of an anionic coordination network based on metal–fullerene units. The structure of this network is closely related to a type I gas clathrate (see picture) in w...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2011-08, Vol.50 (36), p.8279-8282
Main Authors: Bacsa, John, Less, Robert J., Skelton, Helen E., Soracevic, Zlatko, Steiner, Alexander, Wilson, Thomas C., Wood, Paul T., Wright, Dominic S.
Format: Article
Language:English
Subjects:
clathrates
fullerenes
metal-organic frameworks
X-ray diffraction
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c4773-fb3e6db03b78e9b0142e397d3c021d8c602f3540b38c7b13cc000c88a7a397333
cites cdi_FETCH-LOGICAL-c4773-fb3e6db03b78e9b0142e397d3c021d8c602f3540b38c7b13cc000c88a7a397333
container_end_page 8282
container_issue 36
container_start_page 8279
container_title Angewandte Chemie International Edition
container_volume 50
creator Bacsa, John
Less, Robert J.
Skelton, Helen E.
Soracevic, Zlatko
Steiner, Alexander
Wilson, Thomas C.
Wood, Paul T.
Wright, Dominic S.
description Pump up the volume: Slow crystallization of Na[C5(CN)5], the unsolvated sodium salt of pentacyanocyclopentadienide, gives the first example of an anionic coordination network based on metal–fullerene units. The structure of this network is closely related to a type I gas clathrate (see picture) in which around 66 % of the unit cell volume is occupied by solvent molecules.
doi_str_mv 10.1002/anie.201102783
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1093519183</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3277063681</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4773-fb3e6db03b78e9b0142e397d3c021d8c602f3540b38c7b13cc000c88a7a397333</originalsourceid><addsrcrecordid>eNqFkTFv2zAQhYWiRZOmXTsWBLp0oUvqJJEaDSNyAjhOCyRINoKiTgkTSXRJKYn_fWk4NYoune6G7717uJcknzmbccbS73qwOEsZ5ywVEt4kxzxPOQUh4G3cMwAqZM6Pkg8hPEReSla8T45SLkrgkB8n9_MQsK-7LXEtGe-RVNaHkVRT16HHAenVdoPkAkfd0Ut_F88ZUnnd47Pzj4FcBzvcEU1-dHrQPoqfkFaua8jCOd_YQY_WDWTtGvyYvGt1F_DT6zxJrqvTq8UZXV0uzxfzFTVZDE3bGrBoaga1kFjWjGcpQikaMCzljTQFS1vIM1aDNKLmYAxjzEiphY4YAJwk3_a-G-9-TRhG1dtgsIsB0U1BcVZCzksud-jXf9AHN_khplM850UR74gsUrM9ZbwLwWOrNt722m-jldp1oHYdqEMHUfDl1Xaqe2wO-J-nR6DcA8-2w-1_7NR8fX76tznda20Y8eWg1f5RFQJErm7WS7WqzlYXP9lS3cJvOg2gqw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1516635474</pqid></control><display><type>article</type><title>Assembly of the First Fullerene-Type Metal-Organic Frameworks Using a Planar Five-Fold Coordination Node</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Bacsa, John ; Less, Robert J. ; Skelton, Helen E. ; Soracevic, Zlatko ; Steiner, Alexander ; Wilson, Thomas C. ; Wood, Paul T. ; Wright, Dominic S.</creator><creatorcontrib>Bacsa, John ; Less, Robert J. ; Skelton, Helen E. ; Soracevic, Zlatko ; Steiner, Alexander ; Wilson, Thomas C. ; Wood, Paul T. ; Wright, Dominic S.</creatorcontrib><description>Pump up the volume: Slow crystallization of Na[C5(CN)5], the unsolvated sodium salt of pentacyanocyclopentadienide, gives the first example of an anionic coordination network based on metal–fullerene units. The structure of this network is closely related to a type I gas clathrate (see picture) in which around 66 % of the unit cell volume is occupied by solvent molecules.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201102783</identifier><identifier>PMID: 21793135</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>clathrates ; fullerenes ; metal-organic frameworks ; X-ray diffraction</subject><ispartof>Angewandte Chemie International Edition, 2011-08, Vol.50 (36), p.8279-8282</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><rights>Copyright © 2011 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4773-fb3e6db03b78e9b0142e397d3c021d8c602f3540b38c7b13cc000c88a7a397333</citedby><cites>FETCH-LOGICAL-c4773-fb3e6db03b78e9b0142e397d3c021d8c602f3540b38c7b13cc000c88a7a397333</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21793135$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Bacsa, John</creatorcontrib><creatorcontrib>Less, Robert J.</creatorcontrib><creatorcontrib>Skelton, Helen E.</creatorcontrib><creatorcontrib>Soracevic, Zlatko</creatorcontrib><creatorcontrib>Steiner, Alexander</creatorcontrib><creatorcontrib>Wilson, Thomas C.</creatorcontrib><creatorcontrib>Wood, Paul T.</creatorcontrib><creatorcontrib>Wright, Dominic S.</creatorcontrib><title>Assembly of the First Fullerene-Type Metal-Organic Frameworks Using a Planar Five-Fold Coordination Node</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>Pump up the volume: Slow crystallization of Na[C5(CN)5], the unsolvated sodium salt of pentacyanocyclopentadienide, gives the first example of an anionic coordination network based on metal–fullerene units. The structure of this network is closely related to a type I gas clathrate (see picture) in which around 66 % of the unit cell volume is occupied by solvent molecules.</description><subject>clathrates</subject><subject>fullerenes</subject><subject>metal-organic frameworks</subject><subject>X-ray diffraction</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkTFv2zAQhYWiRZOmXTsWBLp0oUvqJJEaDSNyAjhOCyRINoKiTgkTSXRJKYn_fWk4NYoune6G7717uJcknzmbccbS73qwOEsZ5ywVEt4kxzxPOQUh4G3cMwAqZM6Pkg8hPEReSla8T45SLkrgkB8n9_MQsK-7LXEtGe-RVNaHkVRT16HHAenVdoPkAkfd0Ut_F88ZUnnd47Pzj4FcBzvcEU1-dHrQPoqfkFaua8jCOd_YQY_WDWTtGvyYvGt1F_DT6zxJrqvTq8UZXV0uzxfzFTVZDE3bGrBoaga1kFjWjGcpQikaMCzljTQFS1vIM1aDNKLmYAxjzEiphY4YAJwk3_a-G-9-TRhG1dtgsIsB0U1BcVZCzksud-jXf9AHN_khplM850UR74gsUrM9ZbwLwWOrNt722m-jldp1oHYdqEMHUfDl1Xaqe2wO-J-nR6DcA8-2w-1_7NR8fX76tznda20Y8eWg1f5RFQJErm7WS7WqzlYXP9lS3cJvOg2gqw</recordid><startdate>20110829</startdate><enddate>20110829</enddate><creator>Bacsa, John</creator><creator>Less, Robert J.</creator><creator>Skelton, Helen E.</creator><creator>Soracevic, Zlatko</creator><creator>Steiner, Alexander</creator><creator>Wilson, Thomas C.</creator><creator>Wood, Paul T.</creator><creator>Wright, Dominic S.</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope></search><sort><creationdate>20110829</creationdate><title>Assembly of the First Fullerene-Type Metal-Organic Frameworks Using a Planar Five-Fold Coordination Node</title><author>Bacsa, John ; Less, Robert J. ; Skelton, Helen E. ; Soracevic, Zlatko ; Steiner, Alexander ; Wilson, Thomas C. ; Wood, Paul T. ; Wright, Dominic S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4773-fb3e6db03b78e9b0142e397d3c021d8c602f3540b38c7b13cc000c88a7a397333</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>clathrates</topic><topic>fullerenes</topic><topic>metal-organic frameworks</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bacsa, John</creatorcontrib><creatorcontrib>Less, Robert J.</creatorcontrib><creatorcontrib>Skelton, Helen E.</creatorcontrib><creatorcontrib>Soracevic, Zlatko</creatorcontrib><creatorcontrib>Steiner, Alexander</creatorcontrib><creatorcontrib>Wilson, Thomas C.</creatorcontrib><creatorcontrib>Wood, Paul T.</creatorcontrib><creatorcontrib>Wright, Dominic S.</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bacsa, John</au><au>Less, Robert J.</au><au>Skelton, Helen E.</au><au>Soracevic, Zlatko</au><au>Steiner, Alexander</au><au>Wilson, Thomas C.</au><au>Wood, Paul T.</au><au>Wright, Dominic S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Assembly of the First Fullerene-Type Metal-Organic Frameworks Using a Planar Five-Fold Coordination Node</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2011-08-29</date><risdate>2011</risdate><volume>50</volume><issue>36</issue><spage>8279</spage><epage>8282</epage><pages>8279-8282</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>Pump up the volume: Slow crystallization of Na[C5(CN)5], the unsolvated sodium salt of pentacyanocyclopentadienide, gives the first example of an anionic coordination network based on metal–fullerene units. The structure of this network is closely related to a type I gas clathrate (see picture) in which around 66 % of the unit cell volume is occupied by solvent molecules.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>21793135</pmid><doi>10.1002/anie.201102783</doi><tpages>4</tpages><edition>International ed. in English</edition></addata></record>
fulltext fulltext
identifier ISSN: 1433-7851
ispartof Angewandte Chemie International Edition, 2011-08, Vol.50 (36), p.8279-8282
issn 1433-7851
1521-3773
language eng
recordid cdi_proquest_miscellaneous_1093519183
source Wiley-Blackwell Read & Publish Collection
subjects clathrates
fullerenes
metal-organic frameworks
X-ray diffraction
title Assembly of the First Fullerene-Type Metal-Organic Frameworks Using a Planar Five-Fold Coordination Node
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T00%3A37%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Assembly%20of%20the%20First%20Fullerene-Type%20Metal-Organic%20Frameworks%20Using%20a%20Planar%20Five-Fold%20Coordination%20Node&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Bacsa,%20John&rft.date=2011-08-29&rft.volume=50&rft.issue=36&rft.spage=8279&rft.epage=8282&rft.pages=8279-8282&rft.issn=1433-7851&rft.eissn=1521-3773&rft.coden=ACIEAY&rft_id=info:doi/10.1002/anie.201102783&rft_dat=%3Cproquest_cross%3E3277063681%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c4773-fb3e6db03b78e9b0142e397d3c021d8c602f3540b38c7b13cc000c88a7a397333%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1516635474&rft_id=info:pmid/21793135&rfr_iscdi=true