Investigation of the effect of ZnO nanoparticles on the thermomechanical and microbial properties of hyperbranched polyurethane-urea hybrid composites

• Published in: Polymer international 2012-08, Vol.61 (8), p.1309-1317
• Main Authors: Jena, Kishore K, Narayan, Ramanuj, Raju, Kothapalli V S N
• Format: Article
• Language: English
• Subjects: AFM; Applied sciences; Coatings; Contact angle; Disks; DMTA; Exact sciences and technology; hybrid; Hybrid composites; Microorganisms; Nanoparticles; Physicochemistry of polymers; Polymer industry, paints, wood; Technology of polymers; TGA; Thermogravimetric analysis; Zinc oxide; ZnO
• ISSN: 0959-8103; 1097-0126
• DOI: 10.1002/pi.4209

Hybrid coatings of hyperbranched polyurethane‐urea (HBPUU) containing ZnO nanoparticles were prepared by mixing the hyperbranched polyurethane with the nanoparticles. The films were stored at room temperature and laboratory humidity conditions for one week to yield completely cured hybrid films. The ZnO nanoparticles were found to be well dispersed in the polymer up to 3 wt%. The structure–property relationship of various HBPUU–ZnO hybrid coatings was analysed using a Fourier transform infrared peak deconvolution technique with a Gaussian curve‐fitting procedure, while their viscoelastic, thermomechanical and surface morphology were studied using X‐ray diffraction, dynamic mechanical thermal analysis, thermogravimetric analysis, a universal testing machine, scanning electron microscopy, atomic force microscopy and contact angle instruments. The thermal stability and mechanical properties of the hybrid composite films improved with increasing ZnO content, which was believed to be due to thermal insulation in the presence of nanoparticles. Water contact angle data suggested that the hydrophobic character of the hybrid composites increased with increasing nanoparticle concentration. The antimicrobial property of the HBPUU–ZnO hybrid coatings was studied using the disc diffusion method. HBPUU–ZnO hybrid coatings showed good antimicrobial properties compared to HBPUU. Copyright © 2012 Society of Chemical Industry Hyperbranched polyurethane‐urea (HBPUU)–ZnO hybrid films show good antifungal and antibacterial activity with increasing ZnO concentration. The ZnO‐doped HBPUU films exhibit excellent antibacterial activity, especially for E. coli.