Case of an acid-free cationic polymerization of alkenes. An efficient preparation of poly-β-pinene in hexafluoroisopropanol medium

An unprecedented capacity of hexafluoroiso-propanol to serve both as a sole proton source and polar medium in the cationic polymerization of β-pinene is disclosed. The elaborated procedure is simple-to-operate; it furnishes the respective polymer in a nearly quantitative yield.

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Published in:Journal of polymer research 2012-06, Vol.19 (6), p.1-4, Article 9884
Main Authors: Miroshnichenko, Andrey V., Tumanov, Vasily V., Menshov, Vladimir M., Smit, William A.
Format: Article
Language:English
Subjects:
Alkenes
Cationic polymerization
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Original Paper
Polymer Sciences
Sole
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description An unprecedented capacity of hexafluoroiso-propanol to serve both as a sole proton source and polar medium in the cationic polymerization of β-pinene is disclosed. The elaborated procedure is simple-to-operate; it furnishes the respective polymer in a nearly quantitative yield.
doi_str_mv 10.1007/s10965-012-9884-7
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subjects Alkenes
Cationic polymerization
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Original Paper
Polymer Sciences
Sole
title Case of an acid-free cationic polymerization of alkenes. An efficient preparation of poly-β-pinene in hexafluoroisopropanol medium
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