Synthesis, morphology and microstructure of pomegranate-like hematite (α-Fe2O3) superstructure with high coercivity

• Published in: Journal of alloys and compounds 2012-12, Vol.543, p.118-124
• Main Authors: Tadic, Marin, Citakovic, Nada, Panjan, Matjaz, Stanojevic, Boban, Markovic, Dragana, Jovanovic, Đorđe, Spasojevic, Vojislav
• Format: Article
• Language: English
• Subjects: Coercive force; Coercivity; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Hematite; Hematite (α-Fe2O3); Iron oxide; Magnetic properties; Magnetic properties and materials; Magnetic properties of nanostructures; Materials science; Methods of nanofabrication; Microstructure; Morin temperature; Morphology; Nanostructure; Physics; Scanning electron microscopy; Self-assembly; Self-assembly nanoparticles; Transmission electron microscopy
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2012.07.047

[Display omitted] ► We found superior magnetic properties of the hematite (α-Fe2O3). ► TEM and HRTEM images show a pomegranate-like superstructure. ► Magnetic measurements display high coercivity HC=4350Oe at the room temperature. We found novel and superior magnetic properties of the hematite (α-Fe2O3) that originate from an internal microstructure of particles and strong inter-particle interactions between nanocrystal sub-units. The hematite particles were synthesized by thermal decomposition of iron (III) nitrate without any template or surfactant. The purity, size, crystallinity, morphology, microstructure and magnetic features of the as-prepared particles were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), Raman spectroscopy (RS) and SQUID magnetometry. An XRD study reveals a pure phase of α-Fe2O3 whereas TEM shows α-Fe2O3 spheres with a diameter of about 150nm. RS also shows high quality and purity of the sample. Moreover, TEM and HRTEM images show a pomegranate-like superstructure and evidence that the spherical particles are composed of individual well-crystallized nanoparticle sub-units (self-assembled nanoparticles) with a size of about 20nm. Magnetic measurements display hysteretic behavior at the room temperature with remanent magnetization Mr=0.731emu/g, saturation magnetization MS=6.83emu/g and coercivity HC=4350Oe, as well as the Morin transition at TM=261K. These results and comparison with those in the literature reveal that the sample has extremely high coercivity. The magnetic properties of the sample are discussed in relation to morphology, internal microstructure, surface effects and exchange and dipole–dipole interactions.