Loading…

Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization

UiO-66 is one of the few known water-stable MOFs that are readily amenable to direct ligand substitution. In this work, UiO-66 has been synthesized with amino-, nitro-, methoxy-, and naphthyl-substituted ligands to impart polar, basic, and hydrophobic characteristics. Pure-component CO2, CH4, N2, an...

Full description

Saved in:
Bibliographic Details
Published in:Langmuir 2012-11, Vol.28 (44), p.15606-15613
Main Authors: Cmarik, Gregory E, Kim, Min, Cohen, Seth M, Walton, Krista S
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-a411t-c6eee5d4ac1ff04069c17efa13c1b88585b7bb40f853243a1c01512659d7ef853
cites cdi_FETCH-LOGICAL-a411t-c6eee5d4ac1ff04069c17efa13c1b88585b7bb40f853243a1c01512659d7ef853
container_end_page 15613
container_issue 44
container_start_page 15606
container_title Langmuir
container_volume 28
creator Cmarik, Gregory E
Kim, Min
Cohen, Seth M
Walton, Krista S
description UiO-66 is one of the few known water-stable MOFs that are readily amenable to direct ligand substitution. In this work, UiO-66 has been synthesized with amino-, nitro-, methoxy-, and naphthyl-substituted ligands to impart polar, basic, and hydrophobic characteristics. Pure-component CO2, CH4, N2, and water vapor adsorption isotherms were measured in the materials to study the effect of the functional group on the adsorption behavior. Heats of adsorption were calculated for each pure gas on each material. The results indicate that the amino-functionalized material possesses the best adsorption properties for each pure gas due to a combination of polarity and small functional group size. The naphthyl-functionalized material exhibits a good combination of inhibited water vapor adsorption and high selectivity for CO2 over CH4 and N2.
doi_str_mv 10.1021/la3035352
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1141537602</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1141537602</sourcerecordid><originalsourceid>FETCH-LOGICAL-a411t-c6eee5d4ac1ff04069c17efa13c1b88585b7bb40f853243a1c01512659d7ef853</originalsourceid><addsrcrecordid>eNpt0E1Lw0AQBuBFFFurB_-A7EXQQ3Rnv5IcS7FVKNRDew6bzW7dkiZxNxH015vSWj14mmF4eAdehK6BPACh8FgqRphggp6gIQhKIpHQ-BQNScxZFHPJBugihA0hJGU8PUcDyoiIZQpDNFt2lavWuH0zeFyE2jetqyv86uvG-NaZgGuLV24RSYk_nMJzt1ZVgaddpXdQle5L7ZZLdGZVGczVYY7Qavq0nDxH88XsZTKeR4oDtJGWxhhRcKXBWsKJTDXExipgGvIkEYnI4zznxCaCUc4UaAICqBRp0bP-OEJ3-9zG1--dCW22dUGbslSVqbuQAXAQLJaE9vR-T7WvQ_DGZo13W-U_MyDZrrfs2Ftvbw6xXb41xVH-FNWD2wNQQavSelVpF36dlCBJ8scpHbJN3fm-ovDPw2_ia37t</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1141537602</pqid></control><display><type>article</type><title>Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization</title><source>American Chemical Society:Jisc Collections:American Chemical Society Read &amp; Publish Agreement 2022-2024 (Reading list)</source><creator>Cmarik, Gregory E ; Kim, Min ; Cohen, Seth M ; Walton, Krista S</creator><creatorcontrib>Cmarik, Gregory E ; Kim, Min ; Cohen, Seth M ; Walton, Krista S</creatorcontrib><description>UiO-66 is one of the few known water-stable MOFs that are readily amenable to direct ligand substitution. In this work, UiO-66 has been synthesized with amino-, nitro-, methoxy-, and naphthyl-substituted ligands to impart polar, basic, and hydrophobic characteristics. Pure-component CO2, CH4, N2, and water vapor adsorption isotherms were measured in the materials to study the effect of the functional group on the adsorption behavior. Heats of adsorption were calculated for each pure gas on each material. The results indicate that the amino-functionalized material possesses the best adsorption properties for each pure gas due to a combination of polarity and small functional group size. The naphthyl-functionalized material exhibits a good combination of inhibited water vapor adsorption and high selectivity for CO2 over CH4 and N2.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la3035352</identifier><identifier>PMID: 23057691</identifier><identifier>CODEN: LANGD5</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>Chemistry ; Exact sciences and technology ; General and physical chemistry ; Surface physical chemistry</subject><ispartof>Langmuir, 2012-11, Vol.28 (44), p.15606-15613</ispartof><rights>Copyright © 2012 American Chemical Society</rights><rights>2014 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a411t-c6eee5d4ac1ff04069c17efa13c1b88585b7bb40f853243a1c01512659d7ef853</citedby><cites>FETCH-LOGICAL-a411t-c6eee5d4ac1ff04069c17efa13c1b88585b7bb40f853243a1c01512659d7ef853</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=26616081$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23057691$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cmarik, Gregory E</creatorcontrib><creatorcontrib>Kim, Min</creatorcontrib><creatorcontrib>Cohen, Seth M</creatorcontrib><creatorcontrib>Walton, Krista S</creatorcontrib><title>Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization</title><title>Langmuir</title><addtitle>Langmuir</addtitle><description>UiO-66 is one of the few known water-stable MOFs that are readily amenable to direct ligand substitution. In this work, UiO-66 has been synthesized with amino-, nitro-, methoxy-, and naphthyl-substituted ligands to impart polar, basic, and hydrophobic characteristics. Pure-component CO2, CH4, N2, and water vapor adsorption isotherms were measured in the materials to study the effect of the functional group on the adsorption behavior. Heats of adsorption were calculated for each pure gas on each material. The results indicate that the amino-functionalized material possesses the best adsorption properties for each pure gas due to a combination of polarity and small functional group size. The naphthyl-functionalized material exhibits a good combination of inhibited water vapor adsorption and high selectivity for CO2 over CH4 and N2.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Surface physical chemistry</subject><issn>0743-7463</issn><issn>1520-5827</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNpt0E1Lw0AQBuBFFFurB_-A7EXQQ3Rnv5IcS7FVKNRDew6bzW7dkiZxNxH015vSWj14mmF4eAdehK6BPACh8FgqRphggp6gIQhKIpHQ-BQNScxZFHPJBugihA0hJGU8PUcDyoiIZQpDNFt2lavWuH0zeFyE2jetqyv86uvG-NaZgGuLV24RSYk_nMJzt1ZVgaddpXdQle5L7ZZLdGZVGczVYY7Qavq0nDxH88XsZTKeR4oDtJGWxhhRcKXBWsKJTDXExipgGvIkEYnI4zznxCaCUc4UaAICqBRp0bP-OEJ3-9zG1--dCW22dUGbslSVqbuQAXAQLJaE9vR-T7WvQ_DGZo13W-U_MyDZrrfs2Ftvbw6xXb41xVH-FNWD2wNQQavSelVpF36dlCBJ8scpHbJN3fm-ovDPw2_ia37t</recordid><startdate>20121106</startdate><enddate>20121106</enddate><creator>Cmarik, Gregory E</creator><creator>Kim, Min</creator><creator>Cohen, Seth M</creator><creator>Walton, Krista S</creator><general>American Chemical Society</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20121106</creationdate><title>Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization</title><author>Cmarik, Gregory E ; Kim, Min ; Cohen, Seth M ; Walton, Krista S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a411t-c6eee5d4ac1ff04069c17efa13c1b88585b7bb40f853243a1c01512659d7ef853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Surface physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cmarik, Gregory E</creatorcontrib><creatorcontrib>Kim, Min</creatorcontrib><creatorcontrib>Cohen, Seth M</creatorcontrib><creatorcontrib>Walton, Krista S</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cmarik, Gregory E</au><au>Kim, Min</au><au>Cohen, Seth M</au><au>Walton, Krista S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2012-11-06</date><risdate>2012</risdate><volume>28</volume><issue>44</issue><spage>15606</spage><epage>15613</epage><pages>15606-15613</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><coden>LANGD5</coden><abstract>UiO-66 is one of the few known water-stable MOFs that are readily amenable to direct ligand substitution. In this work, UiO-66 has been synthesized with amino-, nitro-, methoxy-, and naphthyl-substituted ligands to impart polar, basic, and hydrophobic characteristics. Pure-component CO2, CH4, N2, and water vapor adsorption isotherms were measured in the materials to study the effect of the functional group on the adsorption behavior. Heats of adsorption were calculated for each pure gas on each material. The results indicate that the amino-functionalized material possesses the best adsorption properties for each pure gas due to a combination of polarity and small functional group size. The naphthyl-functionalized material exhibits a good combination of inhibited water vapor adsorption and high selectivity for CO2 over CH4 and N2.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>23057691</pmid><doi>10.1021/la3035352</doi><tpages>8</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0743-7463
ispartof Langmuir, 2012-11, Vol.28 (44), p.15606-15613
issn 0743-7463
1520-5827
language eng
recordid cdi_proquest_miscellaneous_1141537602
source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Chemistry
Exact sciences and technology
General and physical chemistry
Surface physical chemistry
title Tuning the Adsorption Properties of UiO-66 via Ligand Functionalization
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-25T09%3A39%3A17IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Tuning%20the%20Adsorption%20Properties%20of%20UiO-66%20via%20Ligand%20Functionalization&rft.jtitle=Langmuir&rft.au=Cmarik,%20Gregory%20E&rft.date=2012-11-06&rft.volume=28&rft.issue=44&rft.spage=15606&rft.epage=15613&rft.pages=15606-15613&rft.issn=0743-7463&rft.eissn=1520-5827&rft.coden=LANGD5&rft_id=info:doi/10.1021/la3035352&rft_dat=%3Cproquest_cross%3E1141537602%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-a411t-c6eee5d4ac1ff04069c17efa13c1b88585b7bb40f853243a1c01512659d7ef853%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1141537602&rft_id=info:pmid/23057691&rfr_iscdi=true