Loading…
New branched oligophenylenefluorenes: Synthesis and spectral-luminescent properties
The fluorenyl dendrimers 1,3,5-tris(2-fluorenyl)benzene and 1,3,5-tris[2-(9,9-dioctylfluorenyl)]benzene, which are model compounds for branched oligophenylenefluorenes, are prepared via the cyclocondensation of unsubstituted and dioctyl-substituted acetylfluorenes, respectively. Branched oligophenyl...
Saved in:
| Published in: | Polymer science. Series B 2011-12, Vol.53 (11-12), p.578-585 |
|---|---|
| Main Authors: | , , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c321t-9960447f25a84e7737f530efa1838884423bb22c0c683b77306551b9cece71673 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c321t-9960447f25a84e7737f530efa1838884423bb22c0c683b77306551b9cece71673 |
| container_end_page | 585 |
| container_issue | 11-12 |
| container_start_page | 578 |
| container_title | Polymer science. Series B |
| container_volume | 53 |
| creator | Khotina, I. A. Shapovalov, A. V. Kushakova, N. S. Sergeev, A. M. Peregudov, A. S. Rusanov, A. L. Babich, S. A. Bystrova, N. A. Kovalev, A. I. |
| description | The fluorenyl dendrimers 1,3,5-tris(2-fluorenyl)benzene and 1,3,5-tris[2-(9,9-dioctylfluorenyl)]benzene, which are model compounds for branched oligophenylenefluorenes, are prepared via the cyclocondensation of unsubstituted and dioctyl-substituted acetylfluorenes, respectively. Branched oligophenylenefluorenes are synthesized via the copolycondensation of phenyl-bis(pinacol diborate) with tribromoarylenes in the presence of the ferrocenyl complex of Pd via the Suzuki reaction A
3
+ B
2
. For solutions of model compounds and oligophenylenefluorenes, absorption and fluorescence spectra are measured and interpreted. In the case of the branched oligomers, no aggregation of luminophore fragments occurs, an advantageous feature that distinguishes the branched oligomers from well-known linear luminescent polymers. |
| doi_str_mv | 10.1134/S1560090411110030 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1221903761</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1221903761</sourcerecordid><originalsourceid>FETCH-LOGICAL-c321t-9960447f25a84e7737f530efa1838884423bb22c0c683b77306551b9cece71673</originalsourceid><addsrcrecordid>eNp9UMtOwzAQtBBIVKUfwC1HLoFdO3YSbqjiJVVwCJwjx920qVwn2IlQ_x5X5YbEXGalmdkXY9cIt4giu6tQKoASMowAEHDGZiilTBVycX6sFaRH_ZItQthBhCgFYjlj1Rt9J43XzmxpnfS22_TDltzBkqPWTr2PHO6T6uDGLYUuJNqtkzCQGb22qZ32XdQNuTEZfD-QHzsKV-yi1TbQ4pfn7PPp8WP5kq7en1-XD6vUCI5jWpYKsixvudRFRnku8lYKoFZjIYqiyDIumoZzA0YVook6KCmxKQ0ZylHlYs5uTn3j6K-Jwljvu7iLtdpRP4UaOccSRK4wWvFkNb4PwVNbD77ba3-oEerjD-s_P4wZfsqE6HUb8vWun7yLF_0T-gElHnKn</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1221903761</pqid></control><display><type>article</type><title>New branched oligophenylenefluorenes: Synthesis and spectral-luminescent properties</title><source>Springer Link</source><creator>Khotina, I. A. ; Shapovalov, A. V. ; Kushakova, N. S. ; Sergeev, A. M. ; Peregudov, A. S. ; Rusanov, A. L. ; Babich, S. A. ; Bystrova, N. A. ; Kovalev, A. I.</creator><creatorcontrib>Khotina, I. A. ; Shapovalov, A. V. ; Kushakova, N. S. ; Sergeev, A. M. ; Peregudov, A. S. ; Rusanov, A. L. ; Babich, S. A. ; Bystrova, N. A. ; Kovalev, A. I.</creatorcontrib><description>The fluorenyl dendrimers 1,3,5-tris(2-fluorenyl)benzene and 1,3,5-tris[2-(9,9-dioctylfluorenyl)]benzene, which are model compounds for branched oligophenylenefluorenes, are prepared via the cyclocondensation of unsubstituted and dioctyl-substituted acetylfluorenes, respectively. Branched oligophenylenefluorenes are synthesized via the copolycondensation of phenyl-bis(pinacol diborate) with tribromoarylenes in the presence of the ferrocenyl complex of Pd via the Suzuki reaction A
3
+ B
2
. For solutions of model compounds and oligophenylenefluorenes, absorption and fluorescence spectra are measured and interpreted. In the case of the branched oligomers, no aggregation of luminophore fragments occurs, an advantageous feature that distinguishes the branched oligomers from well-known linear luminescent polymers.</description><identifier>ISSN: 1560-0904</identifier><identifier>EISSN: 1555-6123</identifier><identifier>DOI: 10.1134/S1560090411110030</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Agglomeration ; Branched ; Chemistry ; Chemistry and Materials Science ; Dendrimers ; Fluorescence ; Functional Polymers ; Mathematical models ; Oligomers ; Polymer Sciences ; Spectra ; Synthesis</subject><ispartof>Polymer science. Series B, 2011-12, Vol.53 (11-12), p.578-585</ispartof><rights>Pleiades Publishing, Ltd. 2011</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c321t-9960447f25a84e7737f530efa1838884423bb22c0c683b77306551b9cece71673</citedby><cites>FETCH-LOGICAL-c321t-9960447f25a84e7737f530efa1838884423bb22c0c683b77306551b9cece71673</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Khotina, I. A.</creatorcontrib><creatorcontrib>Shapovalov, A. V.</creatorcontrib><creatorcontrib>Kushakova, N. S.</creatorcontrib><creatorcontrib>Sergeev, A. M.</creatorcontrib><creatorcontrib>Peregudov, A. S.</creatorcontrib><creatorcontrib>Rusanov, A. L.</creatorcontrib><creatorcontrib>Babich, S. A.</creatorcontrib><creatorcontrib>Bystrova, N. A.</creatorcontrib><creatorcontrib>Kovalev, A. I.</creatorcontrib><title>New branched oligophenylenefluorenes: Synthesis and spectral-luminescent properties</title><title>Polymer science. Series B</title><addtitle>Polym. Sci. Ser. B</addtitle><description>The fluorenyl dendrimers 1,3,5-tris(2-fluorenyl)benzene and 1,3,5-tris[2-(9,9-dioctylfluorenyl)]benzene, which are model compounds for branched oligophenylenefluorenes, are prepared via the cyclocondensation of unsubstituted and dioctyl-substituted acetylfluorenes, respectively. Branched oligophenylenefluorenes are synthesized via the copolycondensation of phenyl-bis(pinacol diborate) with tribromoarylenes in the presence of the ferrocenyl complex of Pd via the Suzuki reaction A
3
+ B
2
. For solutions of model compounds and oligophenylenefluorenes, absorption and fluorescence spectra are measured and interpreted. In the case of the branched oligomers, no aggregation of luminophore fragments occurs, an advantageous feature that distinguishes the branched oligomers from well-known linear luminescent polymers.</description><subject>Agglomeration</subject><subject>Branched</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dendrimers</subject><subject>Fluorescence</subject><subject>Functional Polymers</subject><subject>Mathematical models</subject><subject>Oligomers</subject><subject>Polymer Sciences</subject><subject>Spectra</subject><subject>Synthesis</subject><issn>1560-0904</issn><issn>1555-6123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9UMtOwzAQtBBIVKUfwC1HLoFdO3YSbqjiJVVwCJwjx920qVwn2IlQ_x5X5YbEXGalmdkXY9cIt4giu6tQKoASMowAEHDGZiilTBVycX6sFaRH_ZItQthBhCgFYjlj1Rt9J43XzmxpnfS22_TDltzBkqPWTr2PHO6T6uDGLYUuJNqtkzCQGb22qZ32XdQNuTEZfD-QHzsKV-yi1TbQ4pfn7PPp8WP5kq7en1-XD6vUCI5jWpYKsixvudRFRnku8lYKoFZjIYqiyDIumoZzA0YVook6KCmxKQ0ZylHlYs5uTn3j6K-Jwljvu7iLtdpRP4UaOccSRK4wWvFkNb4PwVNbD77ba3-oEerjD-s_P4wZfsqE6HUb8vWun7yLF_0T-gElHnKn</recordid><startdate>20111201</startdate><enddate>20111201</enddate><creator>Khotina, I. A.</creator><creator>Shapovalov, A. V.</creator><creator>Kushakova, N. S.</creator><creator>Sergeev, A. M.</creator><creator>Peregudov, A. S.</creator><creator>Rusanov, A. L.</creator><creator>Babich, S. A.</creator><creator>Bystrova, N. A.</creator><creator>Kovalev, A. I.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20111201</creationdate><title>New branched oligophenylenefluorenes: Synthesis and spectral-luminescent properties</title><author>Khotina, I. A. ; Shapovalov, A. V. ; Kushakova, N. S. ; Sergeev, A. M. ; Peregudov, A. S. ; Rusanov, A. L. ; Babich, S. A. ; Bystrova, N. A. ; Kovalev, A. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c321t-9960447f25a84e7737f530efa1838884423bb22c0c683b77306551b9cece71673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Agglomeration</topic><topic>Branched</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dendrimers</topic><topic>Fluorescence</topic><topic>Functional Polymers</topic><topic>Mathematical models</topic><topic>Oligomers</topic><topic>Polymer Sciences</topic><topic>Spectra</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Khotina, I. A.</creatorcontrib><creatorcontrib>Shapovalov, A. V.</creatorcontrib><creatorcontrib>Kushakova, N. S.</creatorcontrib><creatorcontrib>Sergeev, A. M.</creatorcontrib><creatorcontrib>Peregudov, A. S.</creatorcontrib><creatorcontrib>Rusanov, A. L.</creatorcontrib><creatorcontrib>Babich, S. A.</creatorcontrib><creatorcontrib>Bystrova, N. A.</creatorcontrib><creatorcontrib>Kovalev, A. I.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer science. Series B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Khotina, I. A.</au><au>Shapovalov, A. V.</au><au>Kushakova, N. S.</au><au>Sergeev, A. M.</au><au>Peregudov, A. S.</au><au>Rusanov, A. L.</au><au>Babich, S. A.</au><au>Bystrova, N. A.</au><au>Kovalev, A. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New branched oligophenylenefluorenes: Synthesis and spectral-luminescent properties</atitle><jtitle>Polymer science. Series B</jtitle><stitle>Polym. Sci. Ser. B</stitle><date>2011-12-01</date><risdate>2011</risdate><volume>53</volume><issue>11-12</issue><spage>578</spage><epage>585</epage><pages>578-585</pages><issn>1560-0904</issn><eissn>1555-6123</eissn><abstract>The fluorenyl dendrimers 1,3,5-tris(2-fluorenyl)benzene and 1,3,5-tris[2-(9,9-dioctylfluorenyl)]benzene, which are model compounds for branched oligophenylenefluorenes, are prepared via the cyclocondensation of unsubstituted and dioctyl-substituted acetylfluorenes, respectively. Branched oligophenylenefluorenes are synthesized via the copolycondensation of phenyl-bis(pinacol diborate) with tribromoarylenes in the presence of the ferrocenyl complex of Pd via the Suzuki reaction A
3
+ B
2
. For solutions of model compounds and oligophenylenefluorenes, absorption and fluorescence spectra are measured and interpreted. In the case of the branched oligomers, no aggregation of luminophore fragments occurs, an advantageous feature that distinguishes the branched oligomers from well-known linear luminescent polymers.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S1560090411110030</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1560-0904 |
| ispartof | Polymer science. Series B, 2011-12, Vol.53 (11-12), p.578-585 |
| issn | 1560-0904 1555-6123 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1221903761 |
| source | Springer Link |
| subjects | Agglomeration Branched Chemistry Chemistry and Materials Science Dendrimers Fluorescence Functional Polymers Mathematical models Oligomers Polymer Sciences Spectra Synthesis |
| title | New branched oligophenylenefluorenes: Synthesis and spectral-luminescent properties |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-04T15%3A52%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=New%20branched%20oligophenylenefluorenes:%20Synthesis%20and%20spectral-luminescent%20properties&rft.jtitle=Polymer%20science.%20Series%20B&rft.au=Khotina,%20I.%20A.&rft.date=2011-12-01&rft.volume=53&rft.issue=11-12&rft.spage=578&rft.epage=585&rft.pages=578-585&rft.issn=1560-0904&rft.eissn=1555-6123&rft_id=info:doi/10.1134/S1560090411110030&rft_dat=%3Cproquest_cross%3E1221903761%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c321t-9960447f25a84e7737f530efa1838884423bb22c0c683b77306551b9cece71673%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1221903761&rft_id=info:pmid/&rfr_iscdi=true |