Effect of organic modification of sepiolite for PA 6 polymer/organoclay nanocomposites

• Published in: Composites science and technology 2010-09, Vol.70 (10), p.1429-1436
• Main Authors: García-López, David, Fernández, José Francisco, Merino, Juan Carlos, Santarén, Julio, Pastor, José María
• Format: Article
• Language: English
• Subjects: A. Nano composite; A. Nanoclays; Applied sciences; B. Thermomechanical properties; Catalysis; Catalysts; Clay (material); Composites; Crystallinity; Dispersions; E. Extrusion; Exact sciences and technology; Forms of application and semi-finished materials; Melts; Nanocomposites; Polymer industry, paints, wood; Sepiolite; Technology of polymers
• ISSN: 0266-3538; 1879-1050
• DOI: 10.1016/j.compscitech.2010.05.020

Polyamide 6 nanocomposites based on sepiolite needle-like clay were prepared via melt extrusion. Sepiolite was organomodified with trimethyl hydrogenated tallow quaternary ammonium (3MTH) by using different amounts of modifier respect to the sepiolite. The effect of modifier/sepiolite ratio on the final nanocomposite properties and the catalytic effect of the sepiolite on the polymeric matrix were evaluated. The presence of organomodified sepiolite on the polymer matrix favoured the crystallinity of the PA 6. The catalytic effect of the sepiolite was reduced as the modifier amount increased. The elastic modulus and Heat Deflection Temperature (HDT) in PA 6/organosepiolite nanocomposites increased ∼2.5 times respect to the neat PA 6 matrix. The higher the modification grade the better the dispersion and orientation of needle-like sepiolite clay were attained. This effect supported the reinforcement efficiency of organosepiolites with high modifier content.