Loading…
Synthesis, crystal growth and characterization of an organic NLO material: Bis(2-aminopyridinium) maleate
A novel organic nonlinear optical material bis(2-aminopyridinium) maleate (B2AM) was synthesized and crystals were grown from aqueous solution. The solubility and metastable zone width were determined. Single crystal X-ray diffraction and Fourier transform infrared spectral analysis were carried out...
Saved in:
| Published in: | Physica. B, Condensed matter Condensed matter, 2010-08, Vol.405 (16), p.3441-3445 |
|---|---|
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c366t-6ca52661689b59e1dc7a571a8b53abdbf736c574eda599769b6b102b6b6d6cf3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c366t-6ca52661689b59e1dc7a571a8b53abdbf736c574eda599769b6b102b6b6d6cf3 |
| container_end_page | 3445 |
| container_issue | 16 |
| container_start_page | 3441 |
| container_title | Physica. B, Condensed matter |
| container_volume | 405 |
| creator | Dhanaraj, P.V. Rajesh, N.P. Bhagavannarayana, G. |
| description | A novel organic nonlinear optical material bis(2-aminopyridinium) maleate (B2AM) was synthesized and crystals were grown from aqueous solution. The solubility and metastable zone width were determined. Single crystal X-ray diffraction and Fourier transform infrared spectral analysis were carried out to confirm the B2AM crystals. Crystalline perfection of the as-grown single crystal was studied through multicrystal X-ray diffraction analysis. The thermal characteristics of as-grown crystals were analyzed by thermogravimetric and differential thermal analysis and differential scanning calorimetry. The transmittance of B2AM crystal has been used to calculate the optical band gap of the crystal. The dielectric and mechanical behavior of the crystals were analyzed. The second harmonic conversion efficiency of B2AM was determined using the Kurtz and Perry powder technique; it was observed greater than that of KDP. |
| doi_str_mv | 10.1016/j.physb.2010.05.020 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1266754646</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0921452610004904</els_id><sourcerecordid>1266754646</sourcerecordid><originalsourceid>FETCH-LOGICAL-c366t-6ca52661689b59e1dc7a571a8b53abdbf736c574eda599769b6b102b6b6d6cf3</originalsourceid><addsrcrecordid>eNp9kE1rGzEQhkVpoI7TX9CLLoUUuq6ktSRvoIc05KNgmkNzF7NabXbMruRI64TNr49cmxw7hxmYeebrJeQLZwvOuPqxWWy7KdULwXKGyQUT7AOZ8ZUuC8FL-ZHMWCV4sZRCfSKnKW1YNq75jODfyY-dS5i-UxunNEJPH2N4GTsKvqG2gwh2dBFfYcTgaWhznob4CB4t_bO-pwPsy9Bf0F-YzkUBA_qwnSI26HE3fMtA7zJzRk5a6JP7fIxz8nBz_XB1V6zvb39fXa4LWyo1FspCvlJxtapqWTneWA1Sc1jVsoS6qVtdKiv10jUgq0qrqlY1ZyJ71SjblnNyfhi7jeFp59JoBkzW9T14F3bJ8Dxcy6VaqoyWB9TGkFJ0rdlGHCBOhjOz19VszD9dzV5Xw6TJuuaur8cFkCz0bQRvMb23ipKJSkuZuZ8HzuVnn9FFkyw6b12D0dnRNAH_u-cNPlSQLw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1266754646</pqid></control><display><type>article</type><title>Synthesis, crystal growth and characterization of an organic NLO material: Bis(2-aminopyridinium) maleate</title><source>ScienceDirect Journals</source><creator>Dhanaraj, P.V. ; Rajesh, N.P. ; Bhagavannarayana, G.</creator><creatorcontrib>Dhanaraj, P.V. ; Rajesh, N.P. ; Bhagavannarayana, G.</creatorcontrib><description>A novel organic nonlinear optical material bis(2-aminopyridinium) maleate (B2AM) was synthesized and crystals were grown from aqueous solution. The solubility and metastable zone width were determined. Single crystal X-ray diffraction and Fourier transform infrared spectral analysis were carried out to confirm the B2AM crystals. Crystalline perfection of the as-grown single crystal was studied through multicrystal X-ray diffraction analysis. The thermal characteristics of as-grown crystals were analyzed by thermogravimetric and differential thermal analysis and differential scanning calorimetry. The transmittance of B2AM crystal has been used to calculate the optical band gap of the crystal. The dielectric and mechanical behavior of the crystals were analyzed. The second harmonic conversion efficiency of B2AM was determined using the Kurtz and Perry powder technique; it was observed greater than that of KDP.</description><identifier>ISSN: 0921-4526</identifier><identifier>EISSN: 1873-2135</identifier><identifier>DOI: 10.1016/j.physb.2010.05.020</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Computational efficiency ; Computing time ; Condensed matter ; Condensed matter: electronic structure, electrical, magnetic, and optical properties ; Crystals ; Diffraction ; Exact sciences and technology ; Fundamental areas of phenomenology (including applications) ; High-resolution X-ray diffraction ; Maleates ; Nonlinear optic materials ; Nonlinear optical crystals ; Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity ; Optical materials ; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation ; Optical properties of bulk materials and thin films ; Optics ; Organic compounds ; Physics ; Single crystal growth ; Single crystals ; X-rays</subject><ispartof>Physica. B, Condensed matter, 2010-08, Vol.405 (16), p.3441-3445</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c366t-6ca52661689b59e1dc7a571a8b53abdbf736c574eda599769b6b102b6b6d6cf3</citedby><cites>FETCH-LOGICAL-c366t-6ca52661689b59e1dc7a571a8b53abdbf736c574eda599769b6b102b6b6d6cf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23029755$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Dhanaraj, P.V.</creatorcontrib><creatorcontrib>Rajesh, N.P.</creatorcontrib><creatorcontrib>Bhagavannarayana, G.</creatorcontrib><title>Synthesis, crystal growth and characterization of an organic NLO material: Bis(2-aminopyridinium) maleate</title><title>Physica. B, Condensed matter</title><description>A novel organic nonlinear optical material bis(2-aminopyridinium) maleate (B2AM) was synthesized and crystals were grown from aqueous solution. The solubility and metastable zone width were determined. Single crystal X-ray diffraction and Fourier transform infrared spectral analysis were carried out to confirm the B2AM crystals. Crystalline perfection of the as-grown single crystal was studied through multicrystal X-ray diffraction analysis. The thermal characteristics of as-grown crystals were analyzed by thermogravimetric and differential thermal analysis and differential scanning calorimetry. The transmittance of B2AM crystal has been used to calculate the optical band gap of the crystal. The dielectric and mechanical behavior of the crystals were analyzed. The second harmonic conversion efficiency of B2AM was determined using the Kurtz and Perry powder technique; it was observed greater than that of KDP.</description><subject>Computational efficiency</subject><subject>Computing time</subject><subject>Condensed matter</subject><subject>Condensed matter: electronic structure, electrical, magnetic, and optical properties</subject><subject>Crystals</subject><subject>Diffraction</subject><subject>Exact sciences and technology</subject><subject>Fundamental areas of phenomenology (including applications)</subject><subject>High-resolution X-ray diffraction</subject><subject>Maleates</subject><subject>Nonlinear optic materials</subject><subject>Nonlinear optical crystals</subject><subject>Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity</subject><subject>Optical materials</subject><subject>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</subject><subject>Optical properties of bulk materials and thin films</subject><subject>Optics</subject><subject>Organic compounds</subject><subject>Physics</subject><subject>Single crystal growth</subject><subject>Single crystals</subject><subject>X-rays</subject><issn>0921-4526</issn><issn>1873-2135</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kE1rGzEQhkVpoI7TX9CLLoUUuq6ktSRvoIc05KNgmkNzF7NabXbMruRI64TNr49cmxw7hxmYeebrJeQLZwvOuPqxWWy7KdULwXKGyQUT7AOZ8ZUuC8FL-ZHMWCV4sZRCfSKnKW1YNq75jODfyY-dS5i-UxunNEJPH2N4GTsKvqG2gwh2dBFfYcTgaWhznob4CB4t_bO-pwPsy9Bf0F-YzkUBA_qwnSI26HE3fMtA7zJzRk5a6JP7fIxz8nBz_XB1V6zvb39fXa4LWyo1FspCvlJxtapqWTneWA1Sc1jVsoS6qVtdKiv10jUgq0qrqlY1ZyJ71SjblnNyfhi7jeFp59JoBkzW9T14F3bJ8Dxcy6VaqoyWB9TGkFJ0rdlGHCBOhjOz19VszD9dzV5Xw6TJuuaur8cFkCz0bQRvMb23ipKJSkuZuZ8HzuVnn9FFkyw6b12D0dnRNAH_u-cNPlSQLw</recordid><startdate>20100815</startdate><enddate>20100815</enddate><creator>Dhanaraj, P.V.</creator><creator>Rajesh, N.P.</creator><creator>Bhagavannarayana, G.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20100815</creationdate><title>Synthesis, crystal growth and characterization of an organic NLO material: Bis(2-aminopyridinium) maleate</title><author>Dhanaraj, P.V. ; Rajesh, N.P. ; Bhagavannarayana, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c366t-6ca52661689b59e1dc7a571a8b53abdbf736c574eda599769b6b102b6b6d6cf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Computational efficiency</topic><topic>Computing time</topic><topic>Condensed matter</topic><topic>Condensed matter: electronic structure, electrical, magnetic, and optical properties</topic><topic>Crystals</topic><topic>Diffraction</topic><topic>Exact sciences and technology</topic><topic>Fundamental areas of phenomenology (including applications)</topic><topic>High-resolution X-ray diffraction</topic><topic>Maleates</topic><topic>Nonlinear optic materials</topic><topic>Nonlinear optical crystals</topic><topic>Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity</topic><topic>Optical materials</topic><topic>Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation</topic><topic>Optical properties of bulk materials and thin films</topic><topic>Optics</topic><topic>Organic compounds</topic><topic>Physics</topic><topic>Single crystal growth</topic><topic>Single crystals</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dhanaraj, P.V.</creatorcontrib><creatorcontrib>Rajesh, N.P.</creatorcontrib><creatorcontrib>Bhagavannarayana, G.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Physica. B, Condensed matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dhanaraj, P.V.</au><au>Rajesh, N.P.</au><au>Bhagavannarayana, G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, crystal growth and characterization of an organic NLO material: Bis(2-aminopyridinium) maleate</atitle><jtitle>Physica. B, Condensed matter</jtitle><date>2010-08-15</date><risdate>2010</risdate><volume>405</volume><issue>16</issue><spage>3441</spage><epage>3445</epage><pages>3441-3445</pages><issn>0921-4526</issn><eissn>1873-2135</eissn><abstract>A novel organic nonlinear optical material bis(2-aminopyridinium) maleate (B2AM) was synthesized and crystals were grown from aqueous solution. The solubility and metastable zone width were determined. Single crystal X-ray diffraction and Fourier transform infrared spectral analysis were carried out to confirm the B2AM crystals. Crystalline perfection of the as-grown single crystal was studied through multicrystal X-ray diffraction analysis. The thermal characteristics of as-grown crystals were analyzed by thermogravimetric and differential thermal analysis and differential scanning calorimetry. The transmittance of B2AM crystal has been used to calculate the optical band gap of the crystal. The dielectric and mechanical behavior of the crystals were analyzed. The second harmonic conversion efficiency of B2AM was determined using the Kurtz and Perry powder technique; it was observed greater than that of KDP.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><doi>10.1016/j.physb.2010.05.020</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0921-4526 |
| ispartof | Physica. B, Condensed matter, 2010-08, Vol.405 (16), p.3441-3445 |
| issn | 0921-4526 1873-2135 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1266754646 |
| source | ScienceDirect Journals |
| subjects | Computational efficiency Computing time Condensed matter Condensed matter: electronic structure, electrical, magnetic, and optical properties Crystals Diffraction Exact sciences and technology Fundamental areas of phenomenology (including applications) High-resolution X-ray diffraction Maleates Nonlinear optic materials Nonlinear optical crystals Optical constants: refractive index, complex dielectric constant, absorption, reflection and transmission coefficients, emissivity Optical materials Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of bulk materials and thin films Optics Organic compounds Physics Single crystal growth Single crystals X-rays |
| title | Synthesis, crystal growth and characterization of an organic NLO material: Bis(2-aminopyridinium) maleate |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T14%3A11%3A20IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis,%20crystal%20growth%20and%20characterization%20of%20an%20organic%20NLO%20material:%20Bis(2-aminopyridinium)%20maleate&rft.jtitle=Physica.%20B,%20Condensed%20matter&rft.au=Dhanaraj,%20P.V.&rft.date=2010-08-15&rft.volume=405&rft.issue=16&rft.spage=3441&rft.epage=3445&rft.pages=3441-3445&rft.issn=0921-4526&rft.eissn=1873-2135&rft_id=info:doi/10.1016/j.physb.2010.05.020&rft_dat=%3Cproquest_cross%3E1266754646%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c366t-6ca52661689b59e1dc7a571a8b53abdbf736c574eda599769b6b102b6b6d6cf3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1266754646&rft_id=info:pmid/&rfr_iscdi=true |