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Thermally stimulated current spectroscopy applied on defect characterization in semi-insulating Cd0.9Zn0.1Te

Defects exhibiting trapping behaviors in semi-insulating (SI) materials were investigated by thermally stimulated current (TSC) spectroscopy. The variation of measurement conditions during the initial photoexcitation and thermal emission, such as the heating rate, bias voltage, illumination time and...

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Published in:Journal of crystal growth 2012-12, Vol.361, p.25-29
Main Authors: Nan, Ruihua, Jie, Wanqi, Zha, Gangqiang, Wang, Bei, Yu, Hui
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Language:English
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creator Nan, Ruihua
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description Defects exhibiting trapping behaviors in semi-insulating (SI) materials were investigated by thermally stimulated current (TSC) spectroscopy. The variation of measurement conditions during the initial photoexcitation and thermal emission, such as the heating rate, bias voltage, illumination time and delay time, may bring some significant effects on TSC spectra, leading to incomplete characterization of trap levels. In this work, defects with deep levels in the band gap of SI-Cd0.9Zn0.1Te crystal, grown by the modified vertical Bridgman (MVB) method, were studied via TSC measurements. TSC measurement of the SI-CZT sample was performed with the optimized measurement conditions. Ten different traps and a deep donor (EDD) level were characterized from the as-obtained spectrum in the temperature range from 25 to 310K with the aid of simultaneous multiple peak analysis (SIMPA). The origins of these traps were identified in detail as well. ► Defects as trapping centers for SI-CZT material were evaluated by TSC spectroscopy. ► The effects of four different measurement conditions on TSC spectra were analyzed. ► All observed defects of SI-CZT were characterized with SIMPA fitting.
doi_str_mv 10.1016/j.jcrysgro.2012.09.001
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subjects A1. Characterization
A1. Defects
A2. Bridgman technique
B1. Cadmium compounds
B2. Semiconducting cadmium compounds
B2. Semiconducting II–VI materials
Bridgman method
Cross-disciplinary physics: materials science
rheology
Crystal defects
Crystal growth
Exact sciences and technology
Growth from melts
zone melting and refining
Materials science
Methods of crystal growth
physics of crystal growth
Physics
Spectral emissivity
Spectroscopy
Thermal emission
Thermally stimulated current
Voltage
title Thermally stimulated current spectroscopy applied on defect characterization in semi-insulating Cd0.9Zn0.1Te
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