Studies of Formaldehyde-Crosslinked Cellulose: Significance of Swelling at the Time of Cross-Linking

Moisture sorption data of Form C samples have been obtained using a McBain-Bakr sorption balance and these were used to calculate effective area of molecular contact of the cross-linked samples with the Brunauer-Emmet-Teller (BET) equation. A probable explanation is advanced for the maxima and minim...

Full description

Saved in:
Bibliographic Details
Published in:Textile research journal 1970-10, Vol.40 (10), p.940-947
Main Authors: Singh, Balkar, Jain, C.L., Pande, A., Chipalkatti, V.B., Parikh, R.S.
Format: Article
Language:English
Subjects:
Contact
Crosslinking
Mathematical analysis
Moisture
Sorption
Swelling
Textiles
Walls
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites cdi_FETCH-LOGICAL-c271t-6959b18c3ecd052257f4e45307554b4752bbd886626076f404960d16c85755c63
container_end_page 947
container_issue 10
container_start_page 940
container_title Textile research journal
container_volume 40
creator Singh, Balkar
Jain, C.L.
Pande, A.
Chipalkatti, V.B.
Parikh, R.S.
description Moisture sorption data of Form C samples have been obtained using a McBain-Bakr sorption balance and these were used to calculate effective area of molecular contact of the cross-linked samples with the Brunauer-Emmet-Teller (BET) equation. A probable explanation is advanced for the maxima and minima in moisture regains of cross-linked in the swollen state samples and the effective area/HCHO relationship. Attempts have been made to infer the distribution of cross-links trom the moisture sorption data of the cross-linked samples. Iodine accessibility values of formaldehyde-crosslinked fibre and dye pickup studies of formaldehyde-crosslinked fabric support an earlier assumption that the primary wall is ruptured under Form W conditions.
doi_str_mv 10.1177/004051757004001012
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1283694744</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sage_id>10.1177_004051757004001012</sage_id><sourcerecordid>1283694744</sourcerecordid><originalsourceid>FETCH-LOGICAL-c271t-6959b18c3ecd052257f4e45307554b4752bbd886626076f404960d16c85755c63</originalsourceid><addsrcrecordid>eNp9kDFPwzAQhS0EEqXwB5g6spieHdvnjCiigITEAMxWYl8gJa2L3Qz99yQqGxLTnU7fO733GLsWcCsE4hJAgRaocVpAgJAnbCZQGY6o7CmbTXc-EefsIuc1AFiLdsb4634IHeVFbBermDZ1H-jzEIhXKebcd9svCouK-n7oY6ZLdtbWfaar3zln76v7t-qRP788PFV3z9xLFHtuSl02wvqCfAAtpcZWkdIFoNaqUahl0wRrjZEG0LQKVGkgCOOtHglvijm7Of7dpfg9UN67TZf96KLeUhyyE9IWplSo1IjKI-onw4lat0vdpk4HJ8BN3bi_3Yyi5VGU6w9y6zik7RjnP8UPqalg6g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1283694744</pqid></control><display><type>article</type><title>Studies of Formaldehyde-Crosslinked Cellulose: Significance of Swelling at the Time of Cross-Linking</title><source>SAGE Complete Deep Backfile Purchase 2012</source><creator>Singh, Balkar ; Jain, C.L. ; Pande, A. ; Chipalkatti, V.B. ; Parikh, R.S.</creator><creatorcontrib>Singh, Balkar ; Jain, C.L. ; Pande, A. ; Chipalkatti, V.B. ; Parikh, R.S.</creatorcontrib><description>Moisture sorption data of Form C samples have been obtained using a McBain-Bakr sorption balance and these were used to calculate effective area of molecular contact of the cross-linked samples with the Brunauer-Emmet-Teller (BET) equation. A probable explanation is advanced for the maxima and minima in moisture regains of cross-linked in the swollen state samples and the effective area/HCHO relationship. Attempts have been made to infer the distribution of cross-links trom the moisture sorption data of the cross-linked samples. Iodine accessibility values of formaldehyde-crosslinked fibre and dye pickup studies of formaldehyde-crosslinked fabric support an earlier assumption that the primary wall is ruptured under Form W conditions.</description><identifier>ISSN: 0040-5175</identifier><identifier>EISSN: 1746-7748</identifier><identifier>DOI: 10.1177/004051757004001012</identifier><language>eng</language><publisher>Thousand Oaks, CA: SAGE Publications</publisher><subject>Contact ; Crosslinking ; Mathematical analysis ; Moisture ; Sorption ; Swelling ; Textiles ; Walls</subject><ispartof>Textile research journal, 1970-10, Vol.40 (10), p.940-947</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c271t-6959b18c3ecd052257f4e45307554b4752bbd886626076f404960d16c85755c63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://journals.sagepub.com/doi/pdf/10.1177/004051757004001012$$EPDF$$P50$$Gsage$$H</linktopdf><linktohtml>$$Uhttps://journals.sagepub.com/doi/10.1177/004051757004001012$$EHTML$$P50$$Gsage$$H</linktohtml><link.rule.ids>314,776,780,21824,27901,27902,45058,45446</link.rule.ids></links><search><creatorcontrib>Singh, Balkar</creatorcontrib><creatorcontrib>Jain, C.L.</creatorcontrib><creatorcontrib>Pande, A.</creatorcontrib><creatorcontrib>Chipalkatti, V.B.</creatorcontrib><creatorcontrib>Parikh, R.S.</creatorcontrib><title>Studies of Formaldehyde-Crosslinked Cellulose: Significance of Swelling at the Time of Cross-Linking</title><title>Textile research journal</title><description>Moisture sorption data of Form C samples have been obtained using a McBain-Bakr sorption balance and these were used to calculate effective area of molecular contact of the cross-linked samples with the Brunauer-Emmet-Teller (BET) equation. A probable explanation is advanced for the maxima and minima in moisture regains of cross-linked in the swollen state samples and the effective area/HCHO relationship. Attempts have been made to infer the distribution of cross-links trom the moisture sorption data of the cross-linked samples. Iodine accessibility values of formaldehyde-crosslinked fibre and dye pickup studies of formaldehyde-crosslinked fabric support an earlier assumption that the primary wall is ruptured under Form W conditions.</description><subject>Contact</subject><subject>Crosslinking</subject><subject>Mathematical analysis</subject><subject>Moisture</subject><subject>Sorption</subject><subject>Swelling</subject><subject>Textiles</subject><subject>Walls</subject><issn>0040-5175</issn><issn>1746-7748</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1970</creationdate><recordtype>article</recordtype><recordid>eNp9kDFPwzAQhS0EEqXwB5g6spieHdvnjCiigITEAMxWYl8gJa2L3Qz99yQqGxLTnU7fO733GLsWcCsE4hJAgRaocVpAgJAnbCZQGY6o7CmbTXc-EefsIuc1AFiLdsb4634IHeVFbBermDZ1H-jzEIhXKebcd9svCouK-n7oY6ZLdtbWfaar3zln76v7t-qRP788PFV3z9xLFHtuSl02wvqCfAAtpcZWkdIFoNaqUahl0wRrjZEG0LQKVGkgCOOtHglvijm7Of7dpfg9UN67TZf96KLeUhyyE9IWplSo1IjKI-onw4lat0vdpk4HJ8BN3bi_3Yyi5VGU6w9y6zik7RjnP8UPqalg6g</recordid><startdate>197010</startdate><enddate>197010</enddate><creator>Singh, Balkar</creator><creator>Jain, C.L.</creator><creator>Pande, A.</creator><creator>Chipalkatti, V.B.</creator><creator>Parikh, R.S.</creator><general>SAGE Publications</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>197010</creationdate><title>Studies of Formaldehyde-Crosslinked Cellulose</title><author>Singh, Balkar ; Jain, C.L. ; Pande, A. ; Chipalkatti, V.B. ; Parikh, R.S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c271t-6959b18c3ecd052257f4e45307554b4752bbd886626076f404960d16c85755c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1970</creationdate><topic>Contact</topic><topic>Crosslinking</topic><topic>Mathematical analysis</topic><topic>Moisture</topic><topic>Sorption</topic><topic>Swelling</topic><topic>Textiles</topic><topic>Walls</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Singh, Balkar</creatorcontrib><creatorcontrib>Jain, C.L.</creatorcontrib><creatorcontrib>Pande, A.</creatorcontrib><creatorcontrib>Chipalkatti, V.B.</creatorcontrib><creatorcontrib>Parikh, R.S.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Textile research journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Singh, Balkar</au><au>Jain, C.L.</au><au>Pande, A.</au><au>Chipalkatti, V.B.</au><au>Parikh, R.S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Studies of Formaldehyde-Crosslinked Cellulose: Significance of Swelling at the Time of Cross-Linking</atitle><jtitle>Textile research journal</jtitle><date>1970-10</date><risdate>1970</risdate><volume>40</volume><issue>10</issue><spage>940</spage><epage>947</epage><pages>940-947</pages><issn>0040-5175</issn><eissn>1746-7748</eissn><abstract>Moisture sorption data of Form C samples have been obtained using a McBain-Bakr sorption balance and these were used to calculate effective area of molecular contact of the cross-linked samples with the Brunauer-Emmet-Teller (BET) equation. A probable explanation is advanced for the maxima and minima in moisture regains of cross-linked in the swollen state samples and the effective area/HCHO relationship. Attempts have been made to infer the distribution of cross-links trom the moisture sorption data of the cross-linked samples. Iodine accessibility values of formaldehyde-crosslinked fibre and dye pickup studies of formaldehyde-crosslinked fabric support an earlier assumption that the primary wall is ruptured under Form W conditions.</abstract><cop>Thousand Oaks, CA</cop><pub>SAGE Publications</pub><doi>10.1177/004051757004001012</doi><tpages>8</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0040-5175
ispartof Textile research journal, 1970-10, Vol.40 (10), p.940-947
issn 0040-5175
1746-7748
language eng
recordid cdi_proquest_miscellaneous_1283694744
source SAGE Complete Deep Backfile Purchase 2012
subjects Contact
Crosslinking
Mathematical analysis
Moisture
Sorption
Swelling
Textiles
Walls
title Studies of Formaldehyde-Crosslinked Cellulose: Significance of Swelling at the Time of Cross-Linking
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-30T15%3A51%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Studies%20of%20Formaldehyde-Crosslinked%20Cellulose:%20Significance%20of%20Swelling%20at%20the%20Time%20of%20Cross-Linking&rft.jtitle=Textile%20research%20journal&rft.au=Singh,%20Balkar&rft.date=1970-10&rft.volume=40&rft.issue=10&rft.spage=940&rft.epage=947&rft.pages=940-947&rft.issn=0040-5175&rft.eissn=1746-7748&rft_id=info:doi/10.1177/004051757004001012&rft_dat=%3Cproquest_cross%3E1283694744%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c271t-6959b18c3ecd052257f4e45307554b4752bbd886626076f404960d16c85755c63%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1283694744&rft_id=info:pmid/&rft_sage_id=10.1177_004051757004001012&rfr_iscdi=true