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Oxygen sensing by fluorescence quenching of [Cu(btmgp)I]
A fluorescence study of acetonitrile solutions of bis(tetramethylguanidine)propane, copper(I)-iodide and [Cu(btmgp)I] was performed and the chemical reaction of the latter species with O 2 was investigated at room temperature. The actual quenching process via O 2 gassing was studied and an exponenti...
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| Published in: | Journal of luminescence 2010-10, Vol.130 (10), p.1958-1962 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c369t-98a724215ca3a5cdf88df8a2178fc613a92bc34036864bbf317eda02066cc5ec3 |
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| cites | cdi_FETCH-LOGICAL-c369t-98a724215ca3a5cdf88df8a2178fc613a92bc34036864bbf317eda02066cc5ec3 |
| container_end_page | 1962 |
| container_issue | 10 |
| container_start_page | 1958 |
| container_title | Journal of luminescence |
| container_volume | 130 |
| creator | Herres-Pawlis, Sonja Berth, Gerhard Wiedemeier, Volker Schmidt, Ludger Zrenner, Artur Warnecke, Hans-Joachim |
| description | A fluorescence study of acetonitrile solutions of bis(tetramethylguanidine)propane, copper(I)-iodide and [Cu(btmgp)I] was performed and the chemical reaction of the latter species with O
2 was investigated at room temperature. The actual quenching process via O
2 gassing was studied and an exponential dependence of the fluorescence intensity with respect to the complex concentration was observed.
Furthermore the survey was deepened on time resolved fluorescence properties of solved [Cu(btmgp)I] in a wider concentration range. The applicability of this complex for O
2 sensing inside a microreactor system was proven by confocal fluorescence measurements. It was shown that the investigated system can be used for oxygen sensing in the copper concentration range from 10
−2 to 10
−9
mol/l. |
| doi_str_mv | 10.1016/j.jlumin.2010.05.012 |
| format | article |
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2 was investigated at room temperature. The actual quenching process via O
2 gassing was studied and an exponential dependence of the fluorescence intensity with respect to the complex concentration was observed.
Furthermore the survey was deepened on time resolved fluorescence properties of solved [Cu(btmgp)I] in a wider concentration range. The applicability of this complex for O
2 sensing inside a microreactor system was proven by confocal fluorescence measurements. It was shown that the investigated system can be used for oxygen sensing in the copper concentration range from 10
−2 to 10
−9
mol/l.</description><identifier>ISSN: 0022-2313</identifier><identifier>EISSN: 1872-7883</identifier><identifier>DOI: 10.1016/j.jlumin.2010.05.012</identifier><identifier>CODEN: JLUMA8</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Acetonitrile ; Atomic and molecular physics ; Chemical reactions ; Confocal ; Copper ; Detection ; Exact sciences and technology ; Fluorescence ; Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion) ; Fluorescence quenching ; Luminescence ; Microreactors ; Molecular properties and interactions with photons ; N donor ligands ; Oxygen ; Physics ; Quenching</subject><ispartof>Journal of luminescence, 2010-10, Vol.130 (10), p.1958-1962</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c369t-98a724215ca3a5cdf88df8a2178fc613a92bc34036864bbf317eda02066cc5ec3</citedby><cites>FETCH-LOGICAL-c369t-98a724215ca3a5cdf88df8a2178fc613a92bc34036864bbf317eda02066cc5ec3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23086485$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Herres-Pawlis, Sonja</creatorcontrib><creatorcontrib>Berth, Gerhard</creatorcontrib><creatorcontrib>Wiedemeier, Volker</creatorcontrib><creatorcontrib>Schmidt, Ludger</creatorcontrib><creatorcontrib>Zrenner, Artur</creatorcontrib><creatorcontrib>Warnecke, Hans-Joachim</creatorcontrib><title>Oxygen sensing by fluorescence quenching of [Cu(btmgp)I]</title><title>Journal of luminescence</title><description>A fluorescence study of acetonitrile solutions of bis(tetramethylguanidine)propane, copper(I)-iodide and [Cu(btmgp)I] was performed and the chemical reaction of the latter species with O
2 was investigated at room temperature. The actual quenching process via O
2 gassing was studied and an exponential dependence of the fluorescence intensity with respect to the complex concentration was observed.
Furthermore the survey was deepened on time resolved fluorescence properties of solved [Cu(btmgp)I] in a wider concentration range. The applicability of this complex for O
2 sensing inside a microreactor system was proven by confocal fluorescence measurements. It was shown that the investigated system can be used for oxygen sensing in the copper concentration range from 10
−2 to 10
−9
mol/l.</description><subject>Acetonitrile</subject><subject>Atomic and molecular physics</subject><subject>Chemical reactions</subject><subject>Confocal</subject><subject>Copper</subject><subject>Detection</subject><subject>Exact sciences and technology</subject><subject>Fluorescence</subject><subject>Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)</subject><subject>Fluorescence quenching</subject><subject>Luminescence</subject><subject>Microreactors</subject><subject>Molecular properties and interactions with photons</subject><subject>N donor ligands</subject><subject>Oxygen</subject><subject>Physics</subject><subject>Quenching</subject><issn>0022-2313</issn><issn>1872-7883</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAUhYMoOI7-AxfdCOOi9SbpI90IMvgYGJiNrkRCmiZjSl8mrTj_3pQOLl2EC7nn3nPuh9A1hggDTu-qqKrHxrQRAf8FSQSYnKAFZhkJM8boKVoAEBISiuk5unCuAgCas3yB2O7nsFdt4FTrTLsPikOg67GzyknVShV8jb58Tp1OB-_rcVUMzb6_3XxcojMtaqeujnWJ3p4eX9cv4Xb3vFk_bENJ03wIcyYyEhOcSEFFIkvNmH-C4IxpmWIqclJIGgNNWRoXhaY4U6UAAmkqZaIkXaLVvLe3nQ_jBt4Yn62uRau60XFMmDdiWca8NJ6l0nbOWaV5b00j7IFj4BMoXvEZFJ9AcUi4B-XHbo4OwklRaytaadzfLKHgo7HE6-5nnfLnfhtluZNmglQaq-TAy878b_QLawp_cw</recordid><startdate>20101001</startdate><enddate>20101001</enddate><creator>Herres-Pawlis, Sonja</creator><creator>Berth, Gerhard</creator><creator>Wiedemeier, Volker</creator><creator>Schmidt, Ludger</creator><creator>Zrenner, Artur</creator><creator>Warnecke, Hans-Joachim</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20101001</creationdate><title>Oxygen sensing by fluorescence quenching of [Cu(btmgp)I]</title><author>Herres-Pawlis, Sonja ; Berth, Gerhard ; Wiedemeier, Volker ; Schmidt, Ludger ; Zrenner, Artur ; Warnecke, Hans-Joachim</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c369t-98a724215ca3a5cdf88df8a2178fc613a92bc34036864bbf317eda02066cc5ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Acetonitrile</topic><topic>Atomic and molecular physics</topic><topic>Chemical reactions</topic><topic>Confocal</topic><topic>Copper</topic><topic>Detection</topic><topic>Exact sciences and technology</topic><topic>Fluorescence</topic><topic>Fluorescence and phosphorescence; radiationless transitions, quenching (intersystem crossing, internal conversion)</topic><topic>Fluorescence quenching</topic><topic>Luminescence</topic><topic>Microreactors</topic><topic>Molecular properties and interactions with photons</topic><topic>N donor ligands</topic><topic>Oxygen</topic><topic>Physics</topic><topic>Quenching</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Herres-Pawlis, Sonja</creatorcontrib><creatorcontrib>Berth, Gerhard</creatorcontrib><creatorcontrib>Wiedemeier, Volker</creatorcontrib><creatorcontrib>Schmidt, Ludger</creatorcontrib><creatorcontrib>Zrenner, Artur</creatorcontrib><creatorcontrib>Warnecke, Hans-Joachim</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Journal of luminescence</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Herres-Pawlis, Sonja</au><au>Berth, Gerhard</au><au>Wiedemeier, Volker</au><au>Schmidt, Ludger</au><au>Zrenner, Artur</au><au>Warnecke, Hans-Joachim</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Oxygen sensing by fluorescence quenching of [Cu(btmgp)I]</atitle><jtitle>Journal of luminescence</jtitle><date>2010-10-01</date><risdate>2010</risdate><volume>130</volume><issue>10</issue><spage>1958</spage><epage>1962</epage><pages>1958-1962</pages><issn>0022-2313</issn><eissn>1872-7883</eissn><coden>JLUMA8</coden><abstract>A fluorescence study of acetonitrile solutions of bis(tetramethylguanidine)propane, copper(I)-iodide and [Cu(btmgp)I] was performed and the chemical reaction of the latter species with O
2 was investigated at room temperature. The actual quenching process via O
2 gassing was studied and an exponential dependence of the fluorescence intensity with respect to the complex concentration was observed.
Furthermore the survey was deepened on time resolved fluorescence properties of solved [Cu(btmgp)I] in a wider concentration range. The applicability of this complex for O
2 sensing inside a microreactor system was proven by confocal fluorescence measurements. It was shown that the investigated system can be used for oxygen sensing in the copper concentration range from 10
−2 to 10
−9
mol/l.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jlumin.2010.05.012</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-2313 |
| ispartof | Journal of luminescence, 2010-10, Vol.130 (10), p.1958-1962 |
| issn | 0022-2313 1872-7883 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1283698778 |
| source | ScienceDirect Freedom Collection |
| subjects | Acetonitrile Atomic and molecular physics Chemical reactions Confocal Copper Detection Exact sciences and technology Fluorescence Fluorescence and phosphorescence radiationless transitions, quenching (intersystem crossing, internal conversion) Fluorescence quenching Luminescence Microreactors Molecular properties and interactions with photons N donor ligands Oxygen Physics Quenching |
| title | Oxygen sensing by fluorescence quenching of [Cu(btmgp)I] |
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