Cyclometallated gold(III) hydroxides as versatile synthons for Au-N, Au-C complexes and luminescent compounds

The gold(III) hydroxide κ(3)-(C^N^C)*Au(OH) reacts with C-H and N-H compounds and arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl compounds in high yields; some of which show unexpectedly strong modulation of their photoluminescence from yellow to blue [(C^N^C)* =...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2012-07, Vol.48 (58), p.7247-7249
Main Authors: Roşca, Dragoş-Adrian, Smith, Dan A, Bochmann, Manfred
Format: Article
Language:English
Subjects:
Gold
Hydroxides
Modulation
Photoluminescence
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The gold(III) hydroxide κ(3)-(C^N^C)*Au(OH) reacts with C-H and N-H compounds and arylboronic acids to produce a range of perfluoroaryls, N-heterocyclic and alkynyl compounds in high yields; some of which show unexpectedly strong modulation of their photoluminescence from yellow to blue [(C^N^C)* = 2,6-(C(6)H(3)Bu(t))(2)pyridine].
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc33104g