Kinetic resolution of propargylamines viaa highly enantioselective non-enzymatic N-acylation process

The non-enzymatic kinetic resolution of diversely substituted primary propargylic amines is reported featuring a highly selective acetyl transfer using (1S,2S)-1 in conjunction with Aliquat super(TM) 336, affording the corresponding enantio-enriched N-acetylated propargylic amines with unprecedented...

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Published in:Chemical communications (Cambridge, England) England), 2012-10, Vol.48 (85), p.10511-10513
Main Authors: Kolleth, Amandine, Christoph, Sarah, Arseniyadis, Stellios, Cossy, Janine
Format: Article
Language:English
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Amines
Conversion
Selectivity
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container_title Chemical communications (Cambridge, England)
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creator Kolleth, Amandine
Christoph, Sarah
Arseniyadis, Stellios
Cossy, Janine
description The non-enzymatic kinetic resolution of diversely substituted primary propargylic amines is reported featuring a highly selective acetyl transfer using (1S,2S)-1 in conjunction with Aliquat super(TM) 336, affording the corresponding enantio-enriched N-acetylated propargylic amines with unprecedented levels of selectivity (s-factors of up to 193 at 50% conversion).
doi_str_mv 10.1039/c2cc35719d
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subjects Amines
Conversion
Selectivity
title Kinetic resolution of propargylamines viaa highly enantioselective non-enzymatic N-acylation process
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