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Formation of protective layers by 5-chlorobenzotriazole and its mixture with sodium fluphenaminate on low-carbon steel from aqueous solutions

It is shown that introduction of R = Cl substituent into benzotriazole (BTA) structure imparts elevated acidity and hydrophobicity to the molecule and improves the compound’s protective and adsorption properties for low-carbon steel in aqueous solution. The surface layer composition of 5-chloro-BTA...

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Bibliographic Details
Published in:Protection of metals and physical chemistry of surfaces 2012-12, Vol.48 (7), p.773-779
Main Authors: Agafonkina, M. O., Kuznetsov, Yu. I., Andreeva, N. P., Pronin, Yu. E., Kazanskii, L. P.
Format: Article
Language:English
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Summary:It is shown that introduction of R = Cl substituent into benzotriazole (BTA) structure imparts elevated acidity and hydrophobicity to the molecule and improves the compound’s protective and adsorption properties for low-carbon steel in aqueous solution. The surface layer composition of 5-chloro-BTA and a blend thereof with sodium fluphenaminate is revealed by XPES. It is shown that the inhibitors under investigation are located in a position close to vertical on the surface of oxidized St3. The layer thicknesses of the inhibitors under investigation are determined and compared by XPES and ellipsometry.
ISSN:2070-2051
2070-206X
DOI:10.1134/S2070205112070027