Nucleic acid bases in 1-alkyl-3-methylimidazolium acetate ionic liquids: A thermophysical and ionic conductivity analysis

► We report the effect of nucleic acid bases on the ionicity of 1,3-dialkylimidazolium acetate ILs. ► Thermophysical properties of the neat ILs were studied as a function of temperature. ► Effect of nucleobase content on the ILs conductivity, density and viscosity (298K–343K). ► Walden plots were de...

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Bibliographic Details
Published in:The Journal of chemical thermodynamics 2013-02, Vol.57, p.1-8
Main Authors: Araújo, J.M.M., Pereiro, A.B., Alves, F., Marrucho, I.M., Rebelo, L.P.N.
Format: Article
Language:English
Subjects:
1-Alkyl-3-methylimidazolium acetates
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
General. Theory
Ionic conductivity
Nucleobases
Thermophysical properties
Walden plot
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Summary:► We report the effect of nucleic acid bases on the ionicity of 1,3-dialkylimidazolium acetate ILs. ► Thermophysical properties of the neat ILs were studied as a function of temperature. ► Effect of nucleobase content on the ILs conductivity, density and viscosity (298K–343K). ► Walden plots were determined and used to clarify the role of the nucleobases in the ILs ionicity. The use of ionic liquids as a media for dissolving DNA holds great promise for the development of new base materials in electrochemistry. This paper reports the systematic study of the effect of two nucleic acid bases, uracil and adenine, on the ionicity of 1-alkyl-3-methylimidazolium acetates achieved by monitoring several thermodynamic and transport properties. Density, dynamic viscosity, speed of sound, refractive index and ionic conductivity of 1-ethyl-3-methylimidazolium acetate and 1-butyl-3-methylimidazolium acetate were studied as a function of temperature at atmospheric pressure. The thermal expansion coefficients and molar volumes of these ionic liquids were calculated from the experimental density values. The various properties of the binary mixtures 1-ethyl-3-methylimidazolium acetate with uracil or adenine, namely, their ionic conductivity, density and viscosity in the temperature range 298K–343K were determined as a function of the nucleobase content. Walden plots were determined and used to clarify the role of the nucleobases in the ionic liquids ionicity.
ISSN:0021-9614
1096-3626
DOI:10.1016/j.jct.2012.07.022