Aryl iodides as strong inhibitors in gold and gold-based bimetallic quasi-homogeneous catalysis

The strong inhibitor effect of aryl iodides on the quasi-homogenous gold-catalyzed oxidation reaction was described. Aryl iodides were adsorbed on the exposed surface of Au clusters, which affected the accessibility of the nanoclusters to the reacting species and acted as strong inhibitors in cataly...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-03, Vol.49 (25), p.2542-2544
Main Authors: Dhital, Raghu Nath, Kamonsatikul, Choavarit, Somsook, Ekasith, Sato, Yoshinori, Sakurai, Hidehiro
Format: Article
Language:English
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Summary:The strong inhibitor effect of aryl iodides on the quasi-homogenous gold-catalyzed oxidation reaction was described. Aryl iodides were adsorbed on the exposed surface of Au clusters, which affected the accessibility of the nanoclusters to the reacting species and acted as strong inhibitors in catalysis.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc39019e