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A mild method for generation of o-quinone methides under basic conditions. The facile synthesis of trans-2,3-dihydrobenzofurans

A novel and efficient method for the generation of o-quinone methide intermediates was developed from the readily available 2-tosylalkylphenols under the mild basic conditions, and their reactions with sulfur ylides were investigated for the stereoselective synthesis of trans-2,3-dihydrobenzofurans.

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Published in:	Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (16), p.1660-1662
Main Authors:	Chen, Mu-Wang, Cao, Liang-Liang, Ye, Zhi-Shi, Jiang, Guo-Fang, Zhou, Yong-Gui
Format:	Article
Language:	English
Subjects:	Benzofurans - chemical synthesis Benzofurans - chemistry Indolequinones - chemical synthesis Indolequinones - chemistry Molecular Structure Phenols - chemistry Sulfur Synthesis
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creator	Chen, Mu-Wang Cao, Liang-Liang Ye, Zhi-Shi Jiang, Guo-Fang Zhou, Yong-Gui
description	A novel and efficient method for the generation of o-quinone methide intermediates was developed from the readily available 2-tosylalkylphenols under the mild basic conditions, and their reactions with sulfur ylides were investigated for the stereoselective synthesis of trans-2,3-dihydrobenzofurans.
doi_str_mv	10.1039/c3cc37800d
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source	Royal Society of Chemistry
subjects	Benzofurans - chemical synthesis Benzofurans - chemistry Indolequinones - chemical synthesis Indolequinones - chemistry Molecular Structure Phenols - chemistry Sulfur Synthesis
title	A mild method for generation of o-quinone methides under basic conditions. The facile synthesis of trans-2,3-dihydrobenzofurans
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