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Photoreversible Polymer–Surfactant Micelles Using the Molecular Recognition of α‑Cyclodextrin

Photoreversible micelles were achieved by a combination of commercially available components sodium alginate (Alg), tetradecyltrimethylammonium bromide (TTAB), α-cyclodextrin (α-CD), and 4-(phenylazo)benzoic acid (PBA). Under visible light irradiation, α-CD interacted more favorably with PBA than wi...

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Published in:	Langmuir 2013-03, Vol.29 (10), p.3188-3194
Main Authors:	Dong, Zhen-Qiang, Cao, Ya, Han, Xiao-Juan, Fan, Min-Min, Yuan, Qi-Juan, Wang, Yi-Fu, Li, Bang-Jing, Zhang, Sheng
Format:	Article
Language:	English
Subjects:	alpha-Cyclodextrins - chemistry Benzoic Acid - chemistry Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry Micelles Micelles. Thin films Models, Theoretical Polymers - chemistry Surface-Active Agents - chemistry Trimethyl Ammonium Compounds - chemistry Ultraviolet Rays
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cited_by	cdi_FETCH-LOGICAL-a345t-7da6460c374f994e80600c8a2d877b8df09985c6d98f1b76e36ec6646495b70c3
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creator	Dong, Zhen-Qiang Cao, Ya Han, Xiao-Juan Fan, Min-Min Yuan, Qi-Juan Wang, Yi-Fu Li, Bang-Jing Zhang, Sheng
description	Photoreversible micelles were achieved by a combination of commercially available components sodium alginate (Alg), tetradecyltrimethylammonium bromide (TTAB), α-cyclodextrin (α-CD), and 4-(phenylazo)benzoic acid (PBA). Under visible light irradiation, α-CD interacted more favorably with PBA than with alkyl chains of TTAB. Therefore, polymer–surfactant micelles were formed by the self-assembly of Alg and TTAB through electrostatic attraction. After UV irradiation, micelles were disrupted because PBA in the cis form lost its ability to complex with α-CD, and then the latter was interacted with TTAB to prevent the association of alkyl chains of TTAB. On alternating irradiation of this quaternary system with UV and visible light, this reversible micellization process can be recycled many times.
doi_str_mv	10.1021/la304101e
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On alternating irradiation of this quaternary system with UV and visible light, this reversible micellization process can be recycled many times.</description><identifier>ISSN: 0743-7463</identifier><identifier>EISSN: 1520-5827</identifier><identifier>DOI: 10.1021/la304101e</identifier><identifier>PMID: 23373668</identifier><identifier>CODEN: LANGD5</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>alpha-Cyclodextrins - chemistry ; Benzoic Acid - chemistry ; Chemistry ; Colloidal state and disperse state ; Exact sciences and technology ; General and physical chemistry ; Micelles ; Micelles. 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Thin films</topic><topic>Models, Theoretical</topic><topic>Polymers - chemistry</topic><topic>Surface-Active Agents - chemistry</topic><topic>Trimethyl Ammonium Compounds - chemistry</topic><topic>Ultraviolet Rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dong, Zhen-Qiang</creatorcontrib><creatorcontrib>Cao, Ya</creatorcontrib><creatorcontrib>Han, Xiao-Juan</creatorcontrib><creatorcontrib>Fan, Min-Min</creatorcontrib><creatorcontrib>Yuan, Qi-Juan</creatorcontrib><creatorcontrib>Wang, Yi-Fu</creatorcontrib><creatorcontrib>Li, Bang-Jing</creatorcontrib><creatorcontrib>Zhang, Sheng</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Langmuir</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dong, Zhen-Qiang</au><au>Cao, Ya</au><au>Han, Xiao-Juan</au><au>Fan, Min-Min</au><au>Yuan, Qi-Juan</au><au>Wang, Yi-Fu</au><au>Li, Bang-Jing</au><au>Zhang, Sheng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photoreversible Polymer–Surfactant Micelles Using the Molecular Recognition of α‑Cyclodextrin</atitle><jtitle>Langmuir</jtitle><addtitle>Langmuir</addtitle><date>2013-03-12</date><risdate>2013</risdate><volume>29</volume><issue>10</issue><spage>3188</spage><epage>3194</epage><pages>3188-3194</pages><issn>0743-7463</issn><eissn>1520-5827</eissn><coden>LANGD5</coden><abstract>Photoreversible micelles were achieved by a combination of commercially available components sodium alginate (Alg), tetradecyltrimethylammonium bromide (TTAB), α-cyclodextrin (α-CD), and 4-(phenylazo)benzoic acid (PBA). Under visible light irradiation, α-CD interacted more favorably with PBA than with alkyl chains of TTAB. Therefore, polymer–surfactant micelles were formed by the self-assembly of Alg and TTAB through electrostatic attraction. After UV irradiation, micelles were disrupted because PBA in the cis form lost its ability to complex with α-CD, and then the latter was interacted with TTAB to prevent the association of alkyl chains of TTAB. On alternating irradiation of this quaternary system with UV and visible light, this reversible micellization process can be recycled many times.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><pmid>23373668</pmid><doi>10.1021/la304101e</doi><tpages>7</tpages></addata></record>
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source	American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects	alpha-Cyclodextrins - chemistry Benzoic Acid - chemistry Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry Micelles Micelles. Thin films Models, Theoretical Polymers - chemistry Surface-Active Agents - chemistry Trimethyl Ammonium Compounds - chemistry Ultraviolet Rays
title	Photoreversible Polymer–Surfactant Micelles Using the Molecular Recognition of α‑Cyclodextrin
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