Azide-Functionalized Lanthanide-Based Metal–Organic Frameworks Showing Selective CO2 Gas Adsorption and Postsynthetic Cavity Expansion

We report herein selective CO2 gas adsorption by two azide-functionalized lanthanide-based metal–organic frameworks (MOFs). This work also demonstrates that azide-functionalized MOFs can be used for postsynthetic cavity expansion, further corroborated by enhanced gas-sorption data.

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Bibliographic Details
Published in:Inorganic chemistry 2013-04, Vol.52 (7), p.3588-3590
Main Authors: Ganguly, Sumi, Pachfule, Pradip, Bala, Sukhen, Goswami, Arijit, Bhattacharya, Sudeshna, Mondal, Raju
Format: Article
Language:English
Online Access:Get full text
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Description
Summary:We report herein selective CO2 gas adsorption by two azide-functionalized lanthanide-based metal–organic frameworks (MOFs). This work also demonstrates that azide-functionalized MOFs can be used for postsynthetic cavity expansion, further corroborated by enhanced gas-sorption data.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic302823r