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Functionality-type distribution of poly(ethylene oxide) and poly(propylene oxide) macromonomers: Critical-chromatography study
Functionality-type distributions of macromomoners with poly(ethylene oxide) and poly(propylene oxide) chains are studied by chromatography under critical conditions. It is shown that, in the critical separation mode, separation of macromolecules with respect to size disappears and only information o...
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| Published in: | Polymer science. Series A, Chemistry, physics Chemistry, physics, 2013, Vol.55 (1), p.61-64 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c349t-9cf31908ba770f3fbe8dce5f9bff9e94a2797b57e2c50402b58794a3a0b875b03 |
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| cites | cdi_FETCH-LOGICAL-c349t-9cf31908ba770f3fbe8dce5f9bff9e94a2797b57e2c50402b58794a3a0b875b03 |
| container_end_page | 64 |
| container_issue | 1 |
| container_start_page | 61 |
| container_title | Polymer science. Series A, Chemistry, physics |
| container_volume | 55 |
| creator | Rozdina, I. G. Filatova, N. N. Gorshkov, A. V. Evreinov, V. V. |
| description | Functionality-type distributions of macromomoners with poly(ethylene oxide) and poly(propylene oxide) chains are studied by chromatography under critical conditions. It is shown that, in the critical separation mode, separation of macromolecules with respect to size disappears and only information on the functionality-type distributions of the test samples may be derived. The critical conditions are determined experimentally with a normal phase (unmodified silica gel) for poly(propylene oxide) and with a reversed phase C
18
for poly(ethylene oxide). The experimental retention volumes for bifunctional macromolecules are in satisfactory agreement with the values calculated under approximation of the Gaussian chain model. |
| doi_str_mv | 10.1134/S0965545X13010057 |
| format | article |
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18
for poly(ethylene oxide). The experimental retention volumes for bifunctional macromolecules are in satisfactory agreement with the values calculated under approximation of the Gaussian chain model.</description><identifier>ISSN: 0965-545X</identifier><identifier>EISSN: 1555-6107</identifier><identifier>DOI: 10.1134/S0965545X13010057</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Analytical Procedures ; Approximation ; Chemistry ; Chemistry and Materials Science ; Chromatography ; Gaussian ; Macromolecules ; Mathematical analysis ; Oxides ; Polymer Sciences ; Separation ; Silica gel</subject><ispartof>Polymer science. Series A, Chemistry, physics, 2013, Vol.55 (1), p.61-64</ispartof><rights>Pleiades Publishing, Ltd. 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-9cf31908ba770f3fbe8dce5f9bff9e94a2797b57e2c50402b58794a3a0b875b03</citedby><cites>FETCH-LOGICAL-c349t-9cf31908ba770f3fbe8dce5f9bff9e94a2797b57e2c50402b58794a3a0b875b03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Rozdina, I. G.</creatorcontrib><creatorcontrib>Filatova, N. N.</creatorcontrib><creatorcontrib>Gorshkov, A. V.</creatorcontrib><creatorcontrib>Evreinov, V. V.</creatorcontrib><title>Functionality-type distribution of poly(ethylene oxide) and poly(propylene oxide) macromonomers: Critical-chromatography study</title><title>Polymer science. Series A, Chemistry, physics</title><addtitle>Polym. Sci. Ser. A</addtitle><description>Functionality-type distributions of macromomoners with poly(ethylene oxide) and poly(propylene oxide) chains are studied by chromatography under critical conditions. It is shown that, in the critical separation mode, separation of macromolecules with respect to size disappears and only information on the functionality-type distributions of the test samples may be derived. The critical conditions are determined experimentally with a normal phase (unmodified silica gel) for poly(propylene oxide) and with a reversed phase C
18
for poly(ethylene oxide). The experimental retention volumes for bifunctional macromolecules are in satisfactory agreement with the values calculated under approximation of the Gaussian chain model.</description><subject>Analytical Procedures</subject><subject>Approximation</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Gaussian</subject><subject>Macromolecules</subject><subject>Mathematical analysis</subject><subject>Oxides</subject><subject>Polymer Sciences</subject><subject>Separation</subject><subject>Silica gel</subject><issn>0965-545X</issn><issn>1555-6107</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLxDAQhYMouOj-AG89rofqpGk2jTdZXBUWPKjgrSRpshtpm5qkYC_-drOsFxE8Dbz3vWHmIXSB4QpjUl4_A19SWtI3TAADUHaEZphSmi8xsGM029v53j9F8xCsBIyXkIByhr7WY6-idb1obZzyOA06a2yI3spxL2fOZINrp4WOu6nVvc7cp230ZSb65mAM3g2_nE4o7zrXu077cJOtvI1WiTZXuySL6LZeDLspC3FspnN0YkQb9PxnnqHX9d3L6iHfPN0_rm43uSIljzlXhmAOlRSMgSFG6qpRmhoujeGal6JgnEnKdKEolFBIWrGkEgGyYlQCOUOLw9507ceoQ6w7G5RuW9FrN4Yak4IUuIKCJxQf0PRFCF6bevC2E36qMdT7uus_dadMcciExPZb7et3N_rUafgn9A1AhoVu</recordid><startdate>2013</startdate><enddate>2013</enddate><creator>Rozdina, I. G.</creator><creator>Filatova, N. N.</creator><creator>Gorshkov, A. V.</creator><creator>Evreinov, V. V.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>2013</creationdate><title>Functionality-type distribution of poly(ethylene oxide) and poly(propylene oxide) macromonomers: Critical-chromatography study</title><author>Rozdina, I. G. ; Filatova, N. N. ; Gorshkov, A. V. ; Evreinov, V. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c349t-9cf31908ba770f3fbe8dce5f9bff9e94a2797b57e2c50402b58794a3a0b875b03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Analytical Procedures</topic><topic>Approximation</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Gaussian</topic><topic>Macromolecules</topic><topic>Mathematical analysis</topic><topic>Oxides</topic><topic>Polymer Sciences</topic><topic>Separation</topic><topic>Silica gel</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rozdina, I. G.</creatorcontrib><creatorcontrib>Filatova, N. N.</creatorcontrib><creatorcontrib>Gorshkov, A. V.</creatorcontrib><creatorcontrib>Evreinov, V. V.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer science. Series A, Chemistry, physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rozdina, I. G.</au><au>Filatova, N. N.</au><au>Gorshkov, A. V.</au><au>Evreinov, V. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Functionality-type distribution of poly(ethylene oxide) and poly(propylene oxide) macromonomers: Critical-chromatography study</atitle><jtitle>Polymer science. Series A, Chemistry, physics</jtitle><stitle>Polym. Sci. Ser. A</stitle><date>2013</date><risdate>2013</risdate><volume>55</volume><issue>1</issue><spage>61</spage><epage>64</epage><pages>61-64</pages><issn>0965-545X</issn><eissn>1555-6107</eissn><abstract>Functionality-type distributions of macromomoners with poly(ethylene oxide) and poly(propylene oxide) chains are studied by chromatography under critical conditions. It is shown that, in the critical separation mode, separation of macromolecules with respect to size disappears and only information on the functionality-type distributions of the test samples may be derived. The critical conditions are determined experimentally with a normal phase (unmodified silica gel) for poly(propylene oxide) and with a reversed phase C
18
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| fulltext | fulltext |
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| ispartof | Polymer science. Series A, Chemistry, physics, 2013, Vol.55 (1), p.61-64 |
| issn | 0965-545X 1555-6107 |
| language | eng |
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| source | Springer Nature |
| subjects | Analytical Procedures Approximation Chemistry Chemistry and Materials Science Chromatography Gaussian Macromolecules Mathematical analysis Oxides Polymer Sciences Separation Silica gel |
| title | Functionality-type distribution of poly(ethylene oxide) and poly(propylene oxide) macromonomers: Critical-chromatography study |
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