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Covalent bonding of zeolitic imidazolate framework-90 to functionalized silica fibers for solid-phase microextraction

Here we report a covalent bonding approach to fabricate a robust metal-organic framework ZIF-90 coating for solid-phase microextraction. The ZIF-90 bonded fiber exhibits high enhancement factors, wide linearity, excellent reproducibility, and good lifetime for the studied polar endocrine disruptors.

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Published in:	Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (21), p.2142-2144
Main Authors:	Yu, Li-Qing, Yan, Xiu-Ping
Format:	Article
Language:	English
Subjects:	Acrylic Resins - chemistry Benzhydryl Compounds - analysis Benzhydryl Compounds - isolation & purification Bonding Chromatography, Gas Coating Covalence Dimethylpolysiloxanes - chemistry Endocrine disruptors Endocrine Disruptors - analysis Endocrine Disruptors - isolation & purification Fibers Imidazoles - chemistry Linearity Phenols - analysis Phenols - isolation & purification Polyvinyls - chemistry Reproducibility Silicon dioxide Silicon Dioxide - chemistry Solid Phase Microextraction Temperature Zeolites - chemistry
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creator	Yu, Li-Qing Yan, Xiu-Ping
description	Here we report a covalent bonding approach to fabricate a robust metal-organic framework ZIF-90 coating for solid-phase microextraction. The ZIF-90 bonded fiber exhibits high enhancement factors, wide linearity, excellent reproducibility, and good lifetime for the studied polar endocrine disruptors.
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subjects	Acrylic Resins - chemistry Benzhydryl Compounds - analysis Benzhydryl Compounds - isolation & purification Bonding Chromatography, Gas Coating Covalence Dimethylpolysiloxanes - chemistry Endocrine disruptors Endocrine Disruptors - analysis Endocrine Disruptors - isolation & purification Fibers Imidazoles - chemistry Linearity Phenols - analysis Phenols - isolation & purification Polyvinyls - chemistry Reproducibility Silicon dioxide Silicon Dioxide - chemistry Solid Phase Microextraction Temperature Zeolites - chemistry
title	Covalent bonding of zeolitic imidazolate framework-90 to functionalized silica fibers for solid-phase microextraction
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