Comparison of ozone and HO induced conversion of effluent organic matter (EfOM) using ozonation and UV/H2O2 treatment

• Published in: Water research (Oxford) 2013-05, Vol.47 (7), p.2387-2398
• Main Authors: Audenaert, W.T.M., Vandierendonck, D., Van Hulle, S.W.H., Nopens, I.
• Format: Article
• Language: English
• Subjects: Absorbance; Advanced oxidation; Advanced treatment; Applied sciences; Belgium; Biodegradability; Chlorobenzoates - chemistry; Chromatography, Gel; Effluent organic matter (EfOM); Effluents; Exact sciences and technology; General purification processes; HPSEC; Hydrogen Peroxide - chemistry; Hydroxyl Radical - chemistry; Kinetics; Mathematical analysis; Molecular Weight; Organic Chemicals - chemistry; Oxidation; Oxidation-Reduction - radiation effects; Oxygen - chemistry; Ozonation; Ozone; Ozone - chemistry; Pollution; Spectra; Spectral changes; Spectrophotometry, Ultraviolet; Ultraviolet Rays; UV/H2O2; Waste Disposal, Fluid; Wastewaters; Water Quality; Water treatment and pollution
• ISSN: 0043-1354; 1879-2448
• DOI: 10.1016/j.watres.2013.02.003

This study experimentally examined the impact of oxidation on the properties of effluent organic matter (EfOM) using two different oxidation techniques: ozonation and UV/H2O2 treatment. Multiple surrogates for EfOM related to its spectral properties, molecular size, concentration, polarity and biodegradability were used to study the oxidant induced conversions. Spectral calculations as differential absorbance spectra (DAS) and absorbance slope index (ASI) were applied for the first time to describe EfOM oxidation and proved to be useful to unravel differences in working mechanism between ozone and hydroxyl radical (HO) induced transformation of EfOM. Effluent ozonation inherently led to significant HO production as a result of electron transfers between ozone and electron rich moieties of EfOM. HO production increased as function of ozone dose and was strongly correlated to UV absorption at 254 nm (UV254). During the UV moderated process, pseudo steady-state behaviour of the HO concentration was observed. Ozone decomposition was extremely sensitive to EfOM reactivity. Most likely, the degree of dissociation of EfOM controlled its reactivity towards ozone. The pH effect was quantified by calculating the pseudo-first order decay constant for ozone as function of reaction time and pH. Treatment with both processes led to more oxygen rich, less hydrophobic and more biodegradable EfOM. [Display omitted] ► EfOM conversion and HO production during O3 and UV/H2O2 treatment were compared. ► Both techniques affected differential absorbance and absorbance slope index differently. ► Significant HO production occurred during both processes. ► pH extremely impacted EfOM reactivity. ► HO production was strongly correlated to UV absorption at 254 nm during ozonation.