C(sp3)–H Bond Arylations Catalyzed by Well-Defined [Ru(O2CMes)2(p‑cymene)]

The well-characterized ruthenium(II) biscarboxylate complex [Ru(O2CMes)2(p-cymene)] enabled versatile direct (hetero)arylations of C(sp3)–H bonds with low (co)catalyst loading and ample substrate scope. Detailed mechanistic studies provided strong support for a facile and reversible C(sp3)–H bond me...

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Bibliographic Details
Published in:Journal of organic chemistry 2013-04, Vol.78 (8), p.4145-4152
Main Authors: Kumar, N. Y. Phani, Jeyachandran, Rajkumar, Ackermann, Lutz
Format: Article
Language:English
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Summary:The well-characterized ruthenium(II) biscarboxylate complex [Ru(O2CMes)2(p-cymene)] enabled versatile direct (hetero)arylations of C(sp3)–H bonds with low (co)catalyst loading and ample substrate scope. Detailed mechanistic studies provided strong support for a facile and reversible C(sp3)–H bond metalation.
ISSN:0022-3263
1520-6904
DOI:10.1021/jo400658d