Simultaneous control of regioselectivity and enantioselectivity in the hydroxycarbonylation and methoxycarbonylation of vinyl arenes

Using a family of novel mononuclear and dinuclear palladium complexes of phanephos ligands, the simultaneous control of regioselectivity and enantioselectivity in the hydroxycarbonylation and alkoxycarbonylation of styrene derivatives has been realised for the first time.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-04, Vol.49 (32), p.3306-3308
Main Authors: Konrad, Tina M, Durrani, Jamie T, Cobley, Christopher J, Clarke, Matthew L
Format: Article
Language:English
Subjects:
Coordination Complexes - chemistry
Derivatives
Ligands
Palladium
Palladium - chemistry
Stereoisomerism
Styrene - chemistry
Styrenes
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Description
Summary:Using a family of novel mononuclear and dinuclear palladium complexes of phanephos ligands, the simultaneous control of regioselectivity and enantioselectivity in the hydroxycarbonylation and alkoxycarbonylation of styrene derivatives has been realised for the first time.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc41291a