High yield synthesis of a new fullerene linker and its use in the formation of a linear coordination polymer by silver complexation

A new hexakis-fullerene adduct with two 4,5-diazafluorene groups strategically located at trans-1 positions to allow linear polymerization was selectively synthesized in very high yield. By reaction with Ag(triflate), a one dimensional metal-organic coordination polymer was obtained.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-04, Vol.49 (31), p.3209-3211
Main Authors: Peng, Ping, Li, Fang-Fang, Bowles, Faye L, Neti, Venkata S Pavan K, J Metta-Magana, Alejandro, Olmstead, Marilyn M, Balch, Alan L, Echegoyen, Luis
Format: Article
Language:English
Subjects:
Adducts
Complexation
Coordination polymers
Fullerenes
Polymerization
Silver
Synthesis
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Summary:A new hexakis-fullerene adduct with two 4,5-diazafluorene groups strategically located at trans-1 positions to allow linear polymerization was selectively synthesized in very high yield. By reaction with Ag(triflate), a one dimensional metal-organic coordination polymer was obtained.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc40697k