Heterogeneous vibrational relaxation of carbon monoxide

The first results relating to heterogeneous vibrational relaxation of carbon monoxide in an Al 2 O 3 ceramics tube are reported, together with an estimation of its probability. It was found that the probability of heterogeneous relaxation v of the first-excited state of CO on the Al 2 O 3 surface li...

Full description

Saved in:
Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2013-05, Vol.15 (17), p.6215-6218
Main Authors: Grigorian, Galina M, Cenian, Adam
Format: Article
Language:English
Subjects:
Aluminum oxide
Carbon monoxide
Carbon Monoxide - chemistry
Ceramics
Ceramics - chemistry
Physical chemistry
Surface Properties
Tubes
Vibration
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The first results relating to heterogeneous vibrational relaxation of carbon monoxide in an Al 2 O 3 ceramics tube are reported, together with an estimation of its probability. It was found that the probability of heterogeneous relaxation v of the first-excited state of CO on the Al 2 O 3 surface lies in the range (5 to 7) × 10 −2 . The measurements show that the probabilities of heterogeneous relaxation of CO(X 1 Σ, v ) do not depend on the value of v , at least for v = 1, 2 and 3. The first results relating to heterogeneous vibrational relaxation of carbon monoxide in an Al 2 O 3 ceramics tube are reported, together with an estimation of rate constants.
ISSN:1463-9076
1463-9084
DOI:10.1039/c3cp00040k