A facile synthesis of nanostructured magnesium oxide particles for enhanced adsorption performance in reactive blue 19 removal

• Published in: Journal of colloid and interface science 2013-05, Vol.398, p.210-216
• Main Authors: Nga, Nguyen Kim, Hong, Phi Thi Thuy, Lam, Tran Dai, Huy, Tran Quang
• Format: Article
• Language: English
• Subjects: Adsorption; Anthraquinones - chemistry; BET; Cetyltrimethylammonium bromide (CTAB); Chemistry; Colloidal state and disperse state; Environmental treatment; Exact sciences and technology; General and physical chemistry; Magnesium Oxide - chemistry; Magnesium oxide nanoparticles; Nanoparticles - chemistry; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Reactive blue 19; Surface physical chemistry
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2013.02.018

[Display omitted] ► A facile synthesis of MgO nanoplates using cetyltrimethylammonium bromide was presented. ► Mechanism for the formation of nanostructured MgO particles was proposed. ► MgO nanoplates revealed high BET surface areas. ► MgO nanoplates exhibited a highly adsorptive performance for removal of reactive blue 19 dye. Magnesium oxide (MgO) has been known as an excellent adsorbent for a variety of the environmentally polluted compounds. This work describes a synthesis of nanostructured MgO particles via a facile procedure by using cetyltrimethylammonium bromide (CTAB). Powder X-ray diffraction, thermal gravimetric, and differential thermal gravimetry (TGA/DTG) analyses were performed to characterize the physical properties of synthesized MgO particles and field emission-scanning electron microscopy (FE-SEM) was used to observe their morphology, whereas nitrogen adsorption–desorption isotherms and Brunauer–Emmett–Teller (BET) method were used to calculate the total surface areas of the samples. The adsorptive performance was studied by batch experiments for reactive blue (RB) 19 dye removal. The results showed that as-prepared MgO particles revealed hexagonal-like shaped platelets with an average diameter in the range of 49–91nm and a mean thickness of 19–25nm; meanwhile, MgO CTAB-free particles are aggregated, tiny nanoparticles with an average width of 22nm and an average length of 77nm. The maximum adsorption capacity of as-prepared nanostructured MgO for reactive blue (RB) 19 dye was 250mgg−1. Furthermore, the correlation between structural characterization (mean size, pore, surface) of the samples and the adsorption performance was also discussed in details.