Slow magnetic relaxation in a cyano-bridged ferromagnetic {Fe(III)Ni(II)} alternating chain

A cyano-bridged ferromagnetic {Fe(III)Ni(II)} alternating chain {[Fe(pzTp)(CN)3][Ni(chxn)2]}·ClO4·H2O (1) (pzTp = tetrakis(pyrazolyl)borate, chxn = (1R,2R)-1,2-diaminocyclohexane) was synthesized via rational design. Crystal structure analysis and magnetic studies demonstrated that compound had a on...

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Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2013-06, Vol.42 (21), p.7693-7698
Main Authors: Dong, Da-Peng, Zhang, Yan-Juan, Zheng, Hui, Zhuang, Peng-Fei, Zhao, Liang, Xu, Yang, Hu, Jixiang, Liu, Tao, Duan, Chun-Ying
Format: Article
Language:English
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Summary:A cyano-bridged ferromagnetic {Fe(III)Ni(II)} alternating chain {[Fe(pzTp)(CN)3][Ni(chxn)2]}·ClO4·H2O (1) (pzTp = tetrakis(pyrazolyl)borate, chxn = (1R,2R)-1,2-diaminocyclohexane) was synthesized via rational design. Crystal structure analysis and magnetic studies demonstrated that compound had a one-dimensional zigzagging chain-like structure and slow magnetic relaxation.
ISSN:1477-9226
1477-9234
DOI:10.1039/c3dt50273b