Phosphorus(V) Complexes with Acyclic Monoaminocarbene Ligands via Oxidative Addition

(Difluoroorganyl)dimethylamines, RCF2NMe2 (R = H, Ph, tBu), can be used as carbene precursors for phosphorus trifluoride in an oxidative addition reaction. By this method, complexes of sterically nondemanding asymmetric and acyclic carbenes were obtained that are otherwise not accessible.

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Bibliographic Details
Published in:Inorganic chemistry 2013-05, Vol.52 (10), p.5651-5653
Main Authors: Böttcher, Tobias, Bassil, Bassem S, Zhechkov, Lyuben, Röschenthaler, Gerd-Volker
Format: Article
Language:English
Subjects:
Amines - chemistry
Crystallography, X-Ray
Fluorides - chemistry
Ligands
Methane - analogs & derivatives
Methane - chemistry
Models, Molecular
Molecular Structure
Oxidation-Reduction
Phosphorus - chemistry
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Summary:(Difluoroorganyl)dimethylamines, RCF2NMe2 (R = H, Ph, tBu), can be used as carbene precursors for phosphorus trifluoride in an oxidative addition reaction. By this method, complexes of sterically nondemanding asymmetric and acyclic carbenes were obtained that are otherwise not accessible.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic400756z