Ru(II)-catalyzed intermolecular C-H amidation of weakly coordinating ketones

An efficient Ru(II)-catalyzed intermolecular amidation of weakly coordinating ketones with sulfonyl azides via C-H bond activation is described. The reaction proceeds with high functional group tolerance, providing a novel approach to practical ketone-directed intermolecular C-N bond formation in th...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-06, Vol.49 (50), p.5654-5656
Main Authors: Zheng, Qing-Zhong, Liang, Yu-Feng, Qin, Chong, Jiao, Ning
Format: Article
Language:English
Subjects:
Azides - chemistry
Carbon - chemistry
Catalysis
Hydrogen - chemistry
Ketones - chemistry
Ruthenium - chemistry
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Summary:An efficient Ru(II)-catalyzed intermolecular amidation of weakly coordinating ketones with sulfonyl azides via C-H bond activation is described. The reaction proceeds with high functional group tolerance, providing a novel approach to practical ketone-directed intermolecular C-N bond formation in the absence of an additional oxidant.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc42613k