CuH-ZSM‑5 as Hydrocarbon Trap under Cold Start Conditions

• Published in: Environmental science & technology 2013-06, Vol.47 (11), p.5851-5857
• Main Authors: Navlani-García, M, Puértolas, B, Lozano-Castelló, D, Cazorla-Amorós, D, Navarro, M. V, García, T
• Format: Article
• Language: English
• Subjects: Adsorption; Applied sciences; Atmospheric pollution; Copper; Copper - chemistry; Exact sciences and technology; Hydrocarbons; Hydrocarbons - analysis; Metal Nanoparticles; Nanoparticles; Performance evaluation; Pollution; Prevention and purification methods; Protons; Simulation; Transports and other; Vehicle Emissions - analysis; X-Ray Diffraction; Zeolites; Zeolites - chemistry
• ISSN: 0013-936X; 1520-5851
• DOI: 10.1021/es304880b

Cold start tests are carried out to evaluate the performance of copper-exchanged zeolites as hydrocarbon traps under simulated gasoline car exhaust gases, paying special attention to the role of copper in the performance of these zeolites. It is concluded that the partial substitution of the protons in the parent H-ZSM-5 zeolite is highly beneficial for hydrocarbon trapping due to the formation of selective adsorption sites with specific affinity for the different exhaust components. However, it is also observed that uncontrolled exchanging process conditions could lead to the presence of CuO nanoparticles in the zeolite surface, which seem to block the pore structure of the zeolite, decreasing the hydrocarbon trap efficiency. Among all the zeolites studied, the results point out that a CuH-ZSM-5 with a partial substitution of extra-framework protons by copper cations and without any detectable surface CuO nanoparticles is the zeolite that showed the best performance under simulated cold start conditions due to both the high stability and the hydrocarbon retaining capacity of this sample during the consecutive cycles.