Enhanced thermal conductivity of uranium dioxideasilicon carbide composite fuel pellets prepared by Spark Plasma Sintering (SPS)

Uranium dioxide (UO2)a10 vol% silicon carbide (SiC) composite fuel pellets were produced by oxidative sintering and Spark Plasma Sintering (SPS) at a range of temperatures from 1400 to 1600 degree C. Both SiC whiskers and SiC powder particles were utilized. Oxidative sintering was employed over 4 h...

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Bibliographic Details
Published in:Journal of nuclear materials 2013-02, Vol.433 (1-3), p.66-73
Main Authors: Yeo, S, Mckenna, E, Baney, R, Subhash, G, Tulenko, J
Format: Article
Language:English
Online Access:Get full text
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Summary:Uranium dioxide (UO2)a10 vol% silicon carbide (SiC) composite fuel pellets were produced by oxidative sintering and Spark Plasma Sintering (SPS) at a range of temperatures from 1400 to 1600 degree C. Both SiC whiskers and SiC powder particles were utilized. Oxidative sintering was employed over 4 h and the SPS sintering was employed only for 5 min at the highest hold temperature. It was noted that composite pellets sintered by SPS process revealed smaller grain size, reduced formation of chemical products, higher density, and enhanced interfacial contact compared to the pellets made by oxidative sintering. For given volume of SiC, the pellets with powder particles yielded a smaller grain size than pellets with SiC whiskers. Finally thermal conductivity measurements at 100 degree C, 500 degree C, and 900 degree C revealed that SPS sintered UO2aSiC composites exhibited an increase of up to 62% in thermal conductivity compared to UO2 pellets, while the oxidative sintered composite pellets revealed significantly inferior thermal conductivity values. The current study points to the improved processing capabilities of SPS compared to oxidative sintering of UO2aSiC composites.
ISSN:0022-3115