The bis(ethylenedithio)tetrathiafulvalene-based ionic charge-transfer complex with 2,3-dichloro-5,6-dicyano-p-benzoquino ne

In the ionic charge-transfer (CT) complex composed of bis(ethylenedithio)tetrathiafulvalene (ET) and 2,3-dichloro-5,6-dicyano-p-benzoquino ne (DDQ), C10H8S8.C8Cl2N2O2, the donor and acceptor molecules both form centrosymmetric dimers associated by strong face-to-face pi - pi interactions. The disord...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2013-04, Vol.69 (4), p.400-402
Main Authors: Nakagawa, Yuki, Takahashi, Yukihiro, Harada, Jun, Inabe, Tamotsu
Format: Article
Language:English
Subjects:
Columns (structural)
Crystal structure
Crystallography
Dimers
Ladders
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 402
container_issue 4
container_start_page 400
container_title Acta crystallographica. Section C, Crystal structure communications
container_volume 69
creator Nakagawa, Yuki
Takahashi, Yukihiro
Harada, Jun
Inabe, Tamotsu
description In the ionic charge-transfer (CT) complex composed of bis(ethylenedithio)tetrathiafulvalene (ET) and 2,3-dichloro-5,6-dicyano-p-benzoquino ne (DDQ), C10H8S8.C8Cl2N2O2, the donor and acceptor molecules both form centrosymmetric dimers associated by strong face-to-face pi - pi interactions. The disordered DDQ molecules form a one-dimensional pi -stacked column, while the ET molecules form a two-leg ladder through additional short S...S contacts between adjacent pi - pi -bonded dimers. The crystal structure of ET-DDQ revealed in this study will provide a valuable example of the two-leg spin ladder system, which has rarely been reported for ET-based CT complexes.
doi_str_mv 10.1107/S0108270113003685
format article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_1365126973</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1365126973</sourcerecordid><originalsourceid>FETCH-proquest_miscellaneous_13651269733</originalsourceid><addsrcrecordid>eNqVi81OxCAUhYnRxPrzAO5YjsmgFwh0Zm007p39hNJbwTBQgaqjL2-b-AKuzjn5vkPIDYc7zqG9fwEOG9EC5xJA6o06IQ3XAEy1antKmgWzhZ-Ti1LeAEAIIRvys3NIO19WWN0xYMTeV-fTbcWazdzMMIUPswDWmYI99Sl6S60z-RXZ7MQyYKY2HcaAX_RzflOxlqz31oWUE1NrvYyjiYmNrMP4nd4nHxONeEXOBhMKXv_lJVk9Pe4entmYZwdL3R98sRiCiZimsudSKy70tpXyH-ov1u5Zbw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1365126973</pqid></control><display><type>article</type><title>The bis(ethylenedithio)tetrathiafulvalene-based ionic charge-transfer complex with 2,3-dichloro-5,6-dicyano-p-benzoquino ne</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><source>Alma/SFX Local Collection</source><creator>Nakagawa, Yuki ; Takahashi, Yukihiro ; Harada, Jun ; Inabe, Tamotsu</creator><creatorcontrib>Nakagawa, Yuki ; Takahashi, Yukihiro ; Harada, Jun ; Inabe, Tamotsu</creatorcontrib><description>In the ionic charge-transfer (CT) complex composed of bis(ethylenedithio)tetrathiafulvalene (ET) and 2,3-dichloro-5,6-dicyano-p-benzoquino ne (DDQ), C10H8S8.C8Cl2N2O2, the donor and acceptor molecules both form centrosymmetric dimers associated by strong face-to-face pi - pi interactions. The disordered DDQ molecules form a one-dimensional pi -stacked column, while the ET molecules form a two-leg ladder through additional short S...S contacts between adjacent pi - pi -bonded dimers. The crystal structure of ET-DDQ revealed in this study will provide a valuable example of the two-leg spin ladder system, which has rarely been reported for ET-based CT complexes.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270113003685</identifier><language>eng</language><subject>Columns (structural) ; Crystal structure ; Crystallography ; Dimers ; Ladders</subject><ispartof>Acta crystallographica. Section C, Crystal structure communications, 2013-04, Vol.69 (4), p.400-402</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Nakagawa, Yuki</creatorcontrib><creatorcontrib>Takahashi, Yukihiro</creatorcontrib><creatorcontrib>Harada, Jun</creatorcontrib><creatorcontrib>Inabe, Tamotsu</creatorcontrib><title>The bis(ethylenedithio)tetrathiafulvalene-based ionic charge-transfer complex with 2,3-dichloro-5,6-dicyano-p-benzoquino ne</title><title>Acta crystallographica. Section C, Crystal structure communications</title><description>In the ionic charge-transfer (CT) complex composed of bis(ethylenedithio)tetrathiafulvalene (ET) and 2,3-dichloro-5,6-dicyano-p-benzoquino ne (DDQ), C10H8S8.C8Cl2N2O2, the donor and acceptor molecules both form centrosymmetric dimers associated by strong face-to-face pi - pi interactions. The disordered DDQ molecules form a one-dimensional pi -stacked column, while the ET molecules form a two-leg ladder through additional short S...S contacts between adjacent pi - pi -bonded dimers. The crystal structure of ET-DDQ revealed in this study will provide a valuable example of the two-leg spin ladder system, which has rarely been reported for ET-based CT complexes.</description><subject>Columns (structural)</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Dimers</subject><subject>Ladders</subject><issn>0108-2701</issn><issn>1600-5759</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNqVi81OxCAUhYnRxPrzAO5YjsmgFwh0Zm007p39hNJbwTBQgaqjL2-b-AKuzjn5vkPIDYc7zqG9fwEOG9EC5xJA6o06IQ3XAEy1antKmgWzhZ-Ti1LeAEAIIRvys3NIO19WWN0xYMTeV-fTbcWazdzMMIUPswDWmYI99Sl6S60z-RXZ7MQyYKY2HcaAX_RzflOxlqz31oWUE1NrvYyjiYmNrMP4nd4nHxONeEXOBhMKXv_lJVk9Pe4entmYZwdL3R98sRiCiZimsudSKy70tpXyH-ov1u5Zbw</recordid><startdate>20130415</startdate><enddate>20130415</enddate><creator>Nakagawa, Yuki</creator><creator>Takahashi, Yukihiro</creator><creator>Harada, Jun</creator><creator>Inabe, Tamotsu</creator><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20130415</creationdate><title>The bis(ethylenedithio)tetrathiafulvalene-based ionic charge-transfer complex with 2,3-dichloro-5,6-dicyano-p-benzoquino ne</title><author>Nakagawa, Yuki ; Takahashi, Yukihiro ; Harada, Jun ; Inabe, Tamotsu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_13651269733</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Columns (structural)</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Dimers</topic><topic>Ladders</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nakagawa, Yuki</creatorcontrib><creatorcontrib>Takahashi, Yukihiro</creatorcontrib><creatorcontrib>Harada, Jun</creatorcontrib><creatorcontrib>Inabe, Tamotsu</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nakagawa, Yuki</au><au>Takahashi, Yukihiro</au><au>Harada, Jun</au><au>Inabe, Tamotsu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The bis(ethylenedithio)tetrathiafulvalene-based ionic charge-transfer complex with 2,3-dichloro-5,6-dicyano-p-benzoquino ne</atitle><jtitle>Acta crystallographica. Section C, Crystal structure communications</jtitle><date>2013-04-15</date><risdate>2013</risdate><volume>69</volume><issue>4</issue><spage>400</spage><epage>402</epage><pages>400-402</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>In the ionic charge-transfer (CT) complex composed of bis(ethylenedithio)tetrathiafulvalene (ET) and 2,3-dichloro-5,6-dicyano-p-benzoquino ne (DDQ), C10H8S8.C8Cl2N2O2, the donor and acceptor molecules both form centrosymmetric dimers associated by strong face-to-face pi - pi interactions. The disordered DDQ molecules form a one-dimensional pi -stacked column, while the ET molecules form a two-leg ladder through additional short S...S contacts between adjacent pi - pi -bonded dimers. The crystal structure of ET-DDQ revealed in this study will provide a valuable example of the two-leg spin ladder system, which has rarely been reported for ET-based CT complexes.</abstract><doi>10.1107/S0108270113003685</doi></addata></record>
fulltext fulltext
identifier ISSN: 0108-2701
ispartof Acta crystallographica. Section C, Crystal structure communications, 2013-04, Vol.69 (4), p.400-402
issn 0108-2701
1600-5759
language eng
recordid cdi_proquest_miscellaneous_1365126973
source Wiley-Blackwell Read & Publish Collection; Alma/SFX Local Collection
subjects Columns (structural)
Crystal structure
Crystallography
Dimers
Ladders
title The bis(ethylenedithio)tetrathiafulvalene-based ionic charge-transfer complex with 2,3-dichloro-5,6-dicyano-p-benzoquino ne
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T19%3A25%3A55IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20bis(ethylenedithio)tetrathiafulvalene-based%20ionic%20charge-transfer%20complex%20with%202,3-dichloro-5,6-dicyano-p-benzoquino%20ne&rft.jtitle=Acta%20crystallographica.%20Section%20C,%20Crystal%20structure%20communications&rft.au=Nakagawa,%20Yuki&rft.date=2013-04-15&rft.volume=69&rft.issue=4&rft.spage=400&rft.epage=402&rft.pages=400-402&rft.issn=0108-2701&rft.eissn=1600-5759&rft_id=info:doi/10.1107/S0108270113003685&rft_dat=%3Cproquest%3E1365126973%3C/proquest%3E%3Cgrp_id%3Ecdi_FETCH-proquest_miscellaneous_13651269733%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1365126973&rft_id=info:pmid/&rfr_iscdi=true