Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand

A novel mixed-valence Cu(I)-Cu(II) coordination polymer with an infinite two-dimensional structure, [Cu3(I)Cu(II)Br3(3,5-Dmpip-dtc)2]n (3,5-Dmpip-dtc(-) = 3,5-dimethylpiperidine dithiocarbamate), was prepared, and its structure was characterized by X-ray diffraction. It shows semiconducting behavior...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-05, Vol.49 (39), p.4316-4318
Main Authors: Okubo, Takashi, Anma, Haruho, Tanaka, Naoya, Himoto, Kento, Seki, Shu, Saeki, Akinori, Maekawa, Masahiko, Kuroda-Sowa, Takayoshi
Format: Article
Language:English
Subjects:
Carrier transport
Coordination polymers
Crystal structure
Diffraction
Flash photolysis
Ligands
Microwaves
Two dimensional
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A novel mixed-valence Cu(I)-Cu(II) coordination polymer with an infinite two-dimensional structure, [Cu3(I)Cu(II)Br3(3,5-Dmpip-dtc)2]n (3,5-Dmpip-dtc(-) = 3,5-dimethylpiperidine dithiocarbamate), was prepared, and its structure was characterized by X-ray diffraction. It shows semiconducting behavior with a relatively small activation energy and high carrier mobility, which were investigated using impedance spectroscopy and flash photolysis time-resolved microwave conductivity measurements, respectively.
ISSN:1359-7345
1364-548X
DOI:10.1039/c2cc37137e