Functionalization of organic semiconductor crystals viathe Diels-Alder reaction

A surface adlayer is generated on organic single crystals (tetracene and rubrene) using the site specific Diels-Alder reaction and a series of vapor phase dienophiles. X-ray photoelectron spectroscopy (XPS) confirms adsorption on the surfaces of tetracene and rubrene and mass spectrometry demonstrat...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-04, Vol.49 (40), p.4495-4497
Main Authors: Qualizza, Brittni A, Prasad, Srividya, Chiarelli, MPaul, Ciszek, Jacob W
Format: Article
Language:English
Subjects:
Crystals
Diels-Alder reactions
Mass spectrometry
Photoelectron spectroscopy
Surface chemistry
Vapor phases
X-ray photoelectron spectroscopy
X-rays
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Summary:A surface adlayer is generated on organic single crystals (tetracene and rubrene) using the site specific Diels-Alder reaction and a series of vapor phase dienophiles. X-ray photoelectron spectroscopy (XPS) confirms adsorption on the surfaces of tetracene and rubrene and mass spectrometry demonstrates the reaction's applicability to a range of dienophiles.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc40866c