Investigations of direct methanol fuel cell (DMFC) fading mechanisms

• Published in: Journal of power sources 2007-05, Vol.167 (2), p.358-365
• Main Authors: Sarma, Loka Subramanyam, Chen, Ching-Hsiang, Wang, Guo-Rung, Hsueh, Kan-Lin, Huang, Chiou-Ping, Sheu, Hwo-Shuenn, Liu, Ding-Goa, Lee, Jyh-Fu, Hwang, Bing-Joe
• Format: Article
• Language: English
• Subjects: Applied sciences; Direct methanol fuel cell; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fading mechanism; Fuel cells; Gas diffusion layer; Nafion degradation; Ru dissolution; X-ray absorption spectroscopy
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2007.02.020

In this report, we present the microscopic investigations on various fading mechanisms of a direct methanol fuel cell (DMFC). High energy X-ray diffraction (XRD), X-ray absorption spectroscopy (XAS), energy dispersive X-ray spectroscopy (EDX), and Raman spectroscopic analysis were applied to a membrane-electrode-assembly (MEA) before and after fuel cell operation to figure out the various factors causing its fading. High energy XRD analysis of the fresh and faded MEA revealed that the agglomeration of the catalyst particles in the cathode layer of the faded MEA was more significant than in the anode layer of the faded MEA. The XAS analysis demonstrated that the alloying extent of Pt ( J Pt) and Ru ( J Ru) in the anode catalyst was increased and decreased, respectively, from the fresh to the faded MEA, indicating that the Ru environment in the anode catalyst was significantly changed after the fuel cell operation. Based on the X-ray absorption edge jump measurements at the Ru K-edge on the anode catalyst of the fresh and the faded MEA it was found that Ru was dissolved from the Pt-Ru catalyst after the fuel cell operation. Both the Ru K-edge XAS and EDX analysis on the cathode catalyst layer of the faded MEA confirms the presence of Ru environment in the cathode catalyst due to the Ru crossover from the anode to the cathode side. The changes in the membrane and the gas diffusion layer (GDL) after the fuel cell operation were observed from the Raman spectroscopy analysis.