Efficient Dye-Sensitized Photovoltaic Wires Based on an Organic Redox Electrolyte

An organic thiolate/disulfide redox couple with low absorption in the visible region was developed for use in fabricating novel dye-sensitized photovoltaic wires with an aligned carbon nanotube (CNT) fiber as the counter electrode. These flexible wire devices achieved a maximal energy conversion eff...

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Published in:Journal of the American Chemical Society 2013-07, Vol.135 (29), p.10622-10625
Main Authors: Pan, Shaowu, Yang, Zhibin, Li, Houpu, Qiu, Longbin, Sun, Hao, Peng, Huisheng
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Language:English
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cited_by cdi_FETCH-LOGICAL-a381t-35522b88cc83d794768dc0cff02723eb9201994451e05dc463eea2fd618c19fe3
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container_end_page 10625
container_issue 29
container_start_page 10622
container_title Journal of the American Chemical Society
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creator Pan, Shaowu
Yang, Zhibin
Li, Houpu
Qiu, Longbin
Sun, Hao
Peng, Huisheng
description An organic thiolate/disulfide redox couple with low absorption in the visible region was developed for use in fabricating novel dye-sensitized photovoltaic wires with an aligned carbon nanotube (CNT) fiber as the counter electrode. These flexible wire devices achieved a maximal energy conversion efficiency of 7.33%, much higher than the value of 5.97% for the conventional I–/I3 – redox couple. In addition, the aligned CNT fiber also greatly outperforms the conventional Pt counter electrode with a maximal efficiency of 2.06% based on the thiolate/disulfide redox couple.
doi_str_mv 10.1021/ja405012w
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title Efficient Dye-Sensitized Photovoltaic Wires Based on an Organic Redox Electrolyte
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