Rhodium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with Alkenes: Efficient Synthesis of Benzoxaphosphole 1‑Oxides

Rhodium-catalyzed tandem oxidative alkenylation and an intramolecular oxy-Michael reaction were developed using arylphosphonic acid monoethyl esters and alkenes under aerobic conditions, which produced benzoxaphosphole 1-oxides in good to excellent yields.

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Published in:Organic letters 2013-08, Vol.15 (15), p.3986-3989
Main Authors: Ryu, Taekyu, Kim, Jaeeun, Park, Youngchul, Kim, Sanghyuck, Lee, Phil Ho
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Language:English
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cited_by cdi_FETCH-LOGICAL-a315t-595263f8a4962836c29b200f0a17250ff1cdc7ee9378e6761cfa72ee9998fa823
cites cdi_FETCH-LOGICAL-a315t-595263f8a4962836c29b200f0a17250ff1cdc7ee9378e6761cfa72ee9998fa823
container_end_page 3989
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container_title Organic letters
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creator Ryu, Taekyu
Kim, Jaeeun
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Kim, Sanghyuck
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description Rhodium-catalyzed tandem oxidative alkenylation and an intramolecular oxy-Michael reaction were developed using arylphosphonic acid monoethyl esters and alkenes under aerobic conditions, which produced benzoxaphosphole 1-oxides in good to excellent yields.
doi_str_mv 10.1021/ol401775t
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title Rhodium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with Alkenes: Efficient Synthesis of Benzoxaphosphole 1‑Oxides
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