NH/PH Isomerization and a Lewis Pair for Carbon Dioxide Capture

Bis(di-i-propylphosphino)amine 1 reacts with B(C6F5)3 to form an adduct with concomitant N/P H-isomerization. This species reacts smoothly with carbon dioxide. An attempt to prepare an anionic derivative resulted in the formation of a novel heterocycle derived from the PNP ligand and B(C6F5)3.

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Bibliographic Details
Published in:Inorganic chemistry 2013-08, Vol.52 (15), p.8312-8314
Main Authors: Barry, Brian M, Dickie, Diane A, Murphy, Luke J, Clyburne, Jason A. C, Kemp, Richard A
Format: Article
Language:English
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Summary:Bis(di-i-propylphosphino)amine 1 reacts with B(C6F5)3 to form an adduct with concomitant N/P H-isomerization. This species reacts smoothly with carbon dioxide. An attempt to prepare an anionic derivative resulted in the formation of a novel heterocycle derived from the PNP ligand and B(C6F5)3.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic401498r