Iodine recycling via 1,3-migration in iodoindoles under metal catalysis

3-Substituted (indol-2-yl)-α-allenols show divergent patterns of reactivity under metal catalysis. An unprecedented intramolecular 1,3-iodine migration is described.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-09, Vol.49 (71), p.7779-7781
Main Authors: Alcaide, Benito, Almendros, Pedro, Alonso, José M, Cembellín, Sara, Fernández, Israel, del Campo, Teresa Martínez, Torres, M Rosario
Format: Article
Language:English
Subjects:
Carbazoles - chemical synthesis
Carbazoles - chemistry
Catalysis
Cations - chemistry
Crystallography, X-Ray
Cyclization
Iodine - chemistry
Metals - chemistry
Molecular Conformation
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Description
Summary:3-Substituted (indol-2-yl)-α-allenols show divergent patterns of reactivity under metal catalysis. An unprecedented intramolecular 1,3-iodine migration is described.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc44073g