TEMPO-catalyzed Aerobic Oxygenation and Nitrogenation of Olefins via CC Double-Bond Cleavage

A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via CC double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparati...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2013-08, Vol.135 (32), p.11692-11695
Main Authors: Wang, Teng, Jiao, Ning
Format: Article
Language:English
Subjects:
Alkenes - chemistry
Catalysis
Cyclic N-Oxides - chemistry
Nitrogen - chemistry
Oxidants - chemistry
Oxygen - chemistry
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Summary:A novel TEMPO-catalyzed aerobic oxygenation and nitrogenation of hydrocarbons via CC double-bond cleavage has been disclosed. The reaction employs molecular oxygen as the terminal oxidant and oxygen-atom source by metal-free catalysis under mild conditions. This method can be used for the preparation of industrially and pharmaceutically important N- and O-containing motifs, directly from simple and readily available hydrocarbons.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja403824y