Doping of Fullerenes via Anion-Induced Electron Transfer and Its Implication for Surfactant Facilitated High Performance Polymer Solar Cells

Simple and solution‐processible tetrabutyl‐ammonium salts (TBAX) can dope fullerene and its derivatives to achieve conductive thin films (σ as high as 0.56 S/m). The electron transfer between the anions of TBAXs and n‐type semiconductors induces doping without encountering any harsh activation. Thes...

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Published in:Advanced materials (Weinheim) 2013-08, Vol.25 (32), p.4425-4430
Main Authors: Li, Chang-Zhi, Chueh, Chu-Chen, Ding, Feizhi, Yip, Hin-Lap, Liang, Po-Wei, Li, Xiaosong, Jen, Alex K.-Y.
Format: Article
Language:English
Subjects:
Ammonium Compounds - chemistry
Anions - chemistry
conductivity
Electric Conductivity
Fullerenes - chemistry
interfacial material
n-doping
organic electronics
Semiconductors
Solar Energy
Surface-Active Agents - chemistry
tetrabutyl ammonium anions
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cited_by cdi_FETCH-LOGICAL-c4900-8b110c0fd6db371adb5dcea2f1171884185bfff6624cde4e464bbc1ced4cf6d23
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container_end_page 4430
container_issue 32
container_start_page 4425
container_title Advanced materials (Weinheim)
container_volume 25
creator Li, Chang-Zhi
Chueh, Chu-Chen
Ding, Feizhi
Yip, Hin-Lap
Liang, Po-Wei
Li, Xiaosong
Jen, Alex K.-Y.
description Simple and solution‐processible tetrabutyl‐ammonium salts (TBAX) can dope fullerene and its derivatives to achieve conductive thin films (σ as high as 0.56 S/m). The electron transfer between the anions of TBAXs and n‐type semiconductors induces doping without encountering any harsh activation. These provide valid support for the surfactant interfacial doping of fullerene in polymer solar cells for enhanced device performance.
doi_str_mv 10.1002/adma.201300580
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subjects Ammonium Compounds - chemistry
Anions - chemistry
conductivity
Electric Conductivity
Fullerenes - chemistry
interfacial material
n-doping
organic electronics
Semiconductors
Solar Energy
Surface-Active Agents - chemistry
tetrabutyl ammonium anions
title Doping of Fullerenes via Anion-Induced Electron Transfer and Its Implication for Surfactant Facilitated High Performance Polymer Solar Cells
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