Comparative Study of Structure and Permeability of Porous Oxide Films on Aluminum Obtained by Single- and Two-Step Anodization

A comparative study of the structure and transport properties of porous aluminum oxide films obtained by single- and two-step anodization was carried out. It is shown that the oxidation regime significantly affect the number of dead-ended channels, which results in more than twice the variation in m...

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Published in:ACS applied materials & interfaces 2013-08, Vol.5 (16), p.7819-7824
Main Authors: Petukhov, Dmitrii I, Napolskii, Kirill S, Berekchiyan, Mikhail V, Lebedev, Alexander G, Eliseev, Andrey A
Format: Article
Language:English
Subjects:
Aluminum - chemistry
Crystallization
Electrochemistry
Nanostructures - chemistry
Oxides - chemistry
Porosity
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description A comparative study of the structure and transport properties of porous aluminum oxide films obtained by single- and two-step anodization was carried out. It is shown that the oxidation regime significantly affect the number of dead-ended channels, which results in more than twice the variation in membrane permeability. The effect is explained by multiple branching of channels on the initial stages of organization of the porous structure. Branching also occurs on later stages governing mass transport properties of porous anodic alumina films. A model describing transport properties of anodic aluminum oxide membranes based on pore branching on domain boundaries was suggested to fit experimental results of permeance of membranes obtained by both single- and two-step anodization.
doi_str_mv 10.1021/am401585q
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Aluminum - chemistry
Crystallization
Electrochemistry
Nanostructures - chemistry
Oxides - chemistry
Porosity
title Comparative Study of Structure and Permeability of Porous Oxide Films on Aluminum Obtained by Single- and Two-Step Anodization
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