From Thiopheneboroles to Boron-containing Conjugated Macromolecules via Electropolymerization

Electropolymerization of thiophene-3-boroles was successfully carried out in the presence of BF3-OEt2 as roles of supporting electrolyte and lowering their oxidation potentials. The obtained polythiophenes having borole moieties showed broadening energy band due to the extended conjugated system via...

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Bibliographic Details
Published in:Denki kagaku oyobi kōgyō butsuri kagaku 2013/05/05, Vol.81(5), pp.340-342
Main Authors: HAYASHI, Shotaro, KOIZUMI, Toshio
Format: Article
Language:English
Subjects:
Borole
Chains
Conjugated Polymers
Electrochemistry
Electrode potentials
Electrolytes
Electropolymerization
Energy bands
Macromolecules
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Summary:Electropolymerization of thiophene-3-boroles was successfully carried out in the presence of BF3-OEt2 as roles of supporting electrolyte and lowering their oxidation potentials. The obtained polythiophenes having borole moieties showed broadening energy band due to the extended conjugated system via the borole side chain.
ISSN:1344-3542
2186-2451
DOI:10.5796/electrochemistry.81.340